Cs8UIV(UVIO2) 3(Ge3O9)3·3H2O: A mixed-valence uranium germanate with 9-ring channels

Quang Bac Nguyen, Hsin Kuan Liu, Wen Jung Chang, Kwang Hwa Lii

研究成果: 雜誌貢獻期刊論文同行評審

31 引文 斯高帕斯(Scopus)

摘要

A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.

原文???core.languages.en_GB???
頁(從 - 到)4241-4243
頁數3
期刊Inorganic Chemistry
50
發行號10
DOIs
出版狀態已出版 - 16 5月 2011

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