Cs8UIV(UVIO2) 3(Ge3O9)3·3H2O: A mixed-valence uranium germanate with 9-ring channels

Quang Bac Nguyen; Hsin Kuan Liu; Wen Jung Chang; Kwang Hwa Lii

doi:10.1021/ic200508v

Cs₈U^IV(U^VIO₂) ₃(Ge₃O₉)₃·3H₂O: A mixed-valence uranium germanate with 9-ring channels

Quang Bac Nguyen, Hsin Kuan Liu, Wen Jung Chang, Kwang Hwa Lii

化學學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

34 引文斯高帕斯（Scopus）

摘要

A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete U^IVO₆ octahedra and U^VIO₆ tetragonal bipyramids, which are connected by three-membered single-ring Ge ₃O₉^6- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.

原文	???core.languages.en_GB???
頁（從 - 到）	4241-4243
頁數	3
期刊	Inorganic Chemistry
卷	50
發行號	10
DOIs	https://doi.org/10.1021/ic200508v
出版狀態	已出版 - 16 5月 2011

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10.1021/ic200508v

CSD 1783182: Experimental Crystal Structure Determination
Nguyen, Q. B. (貢獻者), Liu, H.-K. (貢獻者), Chang, W.-J. (貢獻者) & Lii, K.-H. (貢獻者), The Cambridge Structural Database, 2011
DOI: 10.25505/fiz.icsd.cc1xvk0b, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cc1xvk0b&sid=DataCite
資料集

引用此

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abstract = "A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.",

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AU - Lii, Kwang Hwa

PY - 2011/5/16

Y1 - 2011/5/16

N2 - A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.

AB - A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.

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Cs8UIV(UVIO2) 3(Ge3O9)3·3H2O: A mixed-valence uranium germanate with 9-ring channels

摘要

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指紋

資料集

CSD 1783182: Experimental Crystal Structure Determination

引用此

Cs₈U^IV(U^VIO₂) ₃(Ge₃O₉)₃·3H₂O: A mixed-valence uranium germanate with 9-ring channels