TY - JOUR
T1 - Cs3Mo5P7O24
T2 - A molybdenum phosphate containing a cubane-like Mo4O3P cluster unit with six MoMo bonds
AU - Wang, Sue Lein
AU - Lii, Kwang Hwa
N1 - Funding Information:
The authors thank the National Science Council of the Republic of China for financial support of this study under Contracts NSC76-0208-MOO7-79 and NSC76-0208-MOOl-47. K.-H. Lii would also like to express thanks for support from the Institute of Chemistry Academia Sinica.
PY - 1988/3
Y1 - 1988/3
N2 - The crystal structure of Cs3Mo5P7O24 has been determined from single-crystal X-ray diffraction data. Cs3Mo5P7O24 crystallizes in the trigonal space group P31c (159) with a = 11.940(4) Å, c = 9.292(2) Å, V = 1147.1(7) Å3, Z = 2, R = 0.0218 (Rw = 0.0258) for 2850 reflections with I > 3 σ(I). The structure consists of large tunnels where the cesium atoms are located. The framework is built up from unusual cubane-like Mo4O3P cluster units with six MoMo bonds, isolated MoO6 octahedra, and pyrophosphate groups.
AB - The crystal structure of Cs3Mo5P7O24 has been determined from single-crystal X-ray diffraction data. Cs3Mo5P7O24 crystallizes in the trigonal space group P31c (159) with a = 11.940(4) Å, c = 9.292(2) Å, V = 1147.1(7) Å3, Z = 2, R = 0.0218 (Rw = 0.0258) for 2850 reflections with I > 3 σ(I). The structure consists of large tunnels where the cesium atoms are located. The framework is built up from unusual cubane-like Mo4O3P cluster units with six MoMo bonds, isolated MoO6 octahedra, and pyrophosphate groups.
UR - http://www.scopus.com/inward/record.url?scp=0023980470&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(88)90079-5
DO - 10.1016/0022-4596(88)90079-5
M3 - 期刊論文
AN - SCOPUS:0023980470
VL - 73
SP - 274
EP - 277
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1
ER -