Cs3Mo5P7O24: A molybdenum phosphate containing a cubane-like Mo4O3P cluster unit with six MoMo bonds

Sue Lein Wang, Kwang Hwa Lii

研究成果: 雜誌貢獻期刊論文同行評審

19 引文 斯高帕斯(Scopus)

摘要

The crystal structure of Cs3Mo5P7O24 has been determined from single-crystal X-ray diffraction data. Cs3Mo5P7O24 crystallizes in the trigonal space group P31c (159) with a = 11.940(4) Å, c = 9.292(2) Å, V = 1147.1(7) Å3, Z = 2, R = 0.0218 (Rw = 0.0258) for 2850 reflections with I > 3 σ(I). The structure consists of large tunnels where the cesium atoms are located. The framework is built up from unusual cubane-like Mo4O3P cluster units with six MoMo bonds, isolated MoO6 octahedra, and pyrophosphate groups.

原文???core.languages.en_GB???
頁(從 - 到)274-277
頁數4
期刊Journal of Solid State Chemistry
73
發行號1
DOIs
出版狀態已出版 - 3月 1988

指紋

深入研究「Cs3Mo5P7O24: A molybdenum phosphate containing a cubane-like Mo4O3P cluster unit with six MoMo bonds」主題。共同形成了獨特的指紋。

引用此