Composition of Titan's ionosphere

We present Cassini Ion and Neutral Mass Spectrometer (INMS) measurements of ion densities on the nightside of Titan from April 16, 2005, and show that a substantial ionosphere exists on the nightside and that complex ion chemistry is operating there. The total ionospheric densities measured both by the INMS and the Cassini Radio and Plasma Wave (RPWS) experiments on Cassini suggest that precipitation from the magnetosphere into the atmosphere of electrons with energies ranging from 25 eV up to about 2 keV is taking place. The absence of ionospheric composition measurements has been a major obstacle to understanding the ionosphere. Seven "families" of ion species, separated in mass-to-charge ratio by 12 Daltons (i.e., the mass of carbon), were observed and establish the importance of hydrocarbon and nitrile chains in the upper atmosphere. Several of the ion species measured by the INMS were predicted by models (e.g., HCNH⁺ and C₂H₅⁺). But the INMS also saw high densities at mass numbers not predicted by models, including mass 18, which we suggest will be ammonium ions (NH₄⁺) produced by reaction of other ion species with neutral ammonia.