Columnar metallomesogens derived from unsymmetrical pyrazoles

Shih Yu Chou, Chun Jung Chen, Shao Ling Tsai, Hwo Shuenn Sheu, Gene Hsiang Lee, Chung K. Lai

研究成果: 雜誌貢獻期刊論文同行評審

23 引文 斯高帕斯(Scopus)

摘要

The synthesis and mesomorphism for two series of unsymmetrical pyrazoles and their nickel(II) complexes were described. This is the first example of nickel complexes exhibiting columnar phase. The derivatives with two alkoxy chains exhibited smectic A or smectic C phases; however, all derivatives with four alkoxy chains formed hexagonal columnar phases. In contrast, all nickel(II) complexes 1a formed hexagonal columnar phases. The crystal and molecular structures of 1-(4-propyloxyphenyl)-2-(3-(4-propyloxyphenyl)-1H-pyrazol-5-yl)ethanone were determined, and it crystallizes in the triclinic space group P-1. The overall molecular shape is considered as rod-shaped. The pyrazole and one phenyl ring were coplanar, however, they were not coplanar with other phenyl ring by a dihedral angle of ca. 66.2°. A dimeric structure formed by an intermolecular H-bond (2.11 Å) and a weak π-π interaction (3.51 Å) was observed, which was probably attributed to the formation of the mesophase. The XRD experiments confirmed their structures of the mesophases.

原文???core.languages.en_GB???
頁(從 - 到)1130-1139
頁數10
期刊Tetrahedron
65
發行號6
DOIs
出版狀態已出版 - 7 2月 2009

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