Characterizations of wet mercury deposition to a remote islet (Pengjiayu) in the subtropical Northwest Pacific Ocean

Thirty-four weekly rainwater samples were collected in 2009 at Pengjiayu, a remote islet in the subtropical Northwest (NW) Pacific Ocean, to study the distribution of rainwater mercury (Hg) concentrations and associated wet deposition fluxes. This is the first study concerning wet Hg deposition to the subtropical NW Pacific Ocean downwind of the East Asian continent, which is the major source region for Hg emissions worldwide. Sample Hg concentrations ranged from 2.25 to 22.33ngL^-1, with a volume-weighted mean (VWM) concentration of 8.85ngL^-1. The annual wet Hg deposition flux was 10.18μgm^-2, about 2.5 times the fluxes measured at sites on the Pacific coast of the USA, supporting the hypothesis that deposition is higher in the western than in the eastern Pacific. Seasonal VWM concentrations were 7.23, 11.58, 7.82, and 9.84ngL^-1, whereas seasonal wet deposition fluxes were 2.14, 3.45, 2.38, and 2.21μgm^-2, for spring, summer, fall and winter, respectively. Higher summer wet Hg deposition was a function of both higher rainwater Hg concentration and greater rainfall. The seasonal pattern of rainwater Hg concentrations was the opposite of the general seasonal pattern of the East Asian air pollutant export. Since there is no significant anthropogenic Hg emission source on the islet of Pengjiayu, the observed high summertime rainwater Hg concentration hints at the importance of Hg⁰ oxidation and/or scavenging of upper-altitude reactive gaseous Hg (RGM) by deep convection. Direct anthropogenic RGM emissions from the East Asian continent may not contribute significantly to the rainwater Hg concentrations, but anthropogenic Hg⁰ emissions could be transported to the upper troposphere or marine boundary layer (MBL) where they can be oxidized to produce RGM, which will then be effectively scavenged by cloud water and rainwater.