Blending of hard and soft organic-inorganic hybrids for use as an effective electrolyte membrane in lithium-ion batteries

Diganta Saikia, Sze Yuan Ho, Yu Ju Chang, Jason Fang, Li Duan Tsai, Hsien Ming Kao

研究成果: 雜誌貢獻期刊論文同行評審

16 引文 斯高帕斯(Scopus)

摘要

In this study, two unique organic-inorganic hybrids are synthesized and optimized to obtain a new type of hybrid blend membrane. A soft hybrid is obtained from reaction of polyetheramine (M-2070) and (3-glycidyloxypropyl)trimethoxysilane (GLYMO), whereas a hard hybrid is prepared from reactions of polyetherdiamine (ED2003), poly(ethylene glycol) diglycidyl ether (PEGDGE) and GLYMO. Both hybrids are finally blended with poly(vinylidene fluoride-co-hexafluoropropylene) (P(VdF-HFP)) to get the hybrid blend membrane and plasticized with 1M LiPF6 in EC/DEC. The successful synthesis of the hybrid blend membrane structure is established from 13C and 29Si solid-state NMR spectroscopy. FTIR results reveal the interactions of different groups of the hybrid blend membrane. The hybrid blend electrolyte possesses maximum ionic conductivity value of 6.9mScm-1 at 30°C and is electrochemically stable up to 5V. The electrochemical performance of the hybrid blend electrolyte assemble in a battery cell with the LiFePO4 cathode exhibits a good cycle life of over 200 cycles with an initial discharge capacity of 150mAhg-1. In addition, coulombic efficiency of 97-99% is maintained for the whole cycles. Our results demonstrate that the present hybrid blend electrolyte can be a potential candidate serving as an effective electrolyte in lithium-ion batteries.

原文???core.languages.en_GB???
頁(從 - 到)59-68
頁數10
期刊Journal of Membrane Science
503
DOIs
出版狀態已出版 - 1 4月 2016

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