Bimetal-organic frameworks derived redox-type composite materials for high-performance energy storage

Electrodes and electroactive materials are crucial components in the development of supercapacitors due to their geometric properties. In this study, bimetal-organic frameworks (Bi-MOFs, ZIF-8@ZIF-67) were utilized as electrode materials for a high-performance hybrid supercapacitor (HSC) by designing a novel synthesis of metallic carbonate hydroxide/oxides. In particular, the Bi-MOFs function as a sacrificial precursor in the synthesis of hollow NiMn(CO₃)_0.5·0·.11H₂O/ZnO@Co₃O₄ CNCs (NM-CH/ZnO@Co₃O₄ CNCs) cubic composite materials by a straightforward low-temperature treatment. The NM-CH/ZnO@Co₃O₄ CNCs exhibited exceptional electrochemical performance with high specific capacity of 196.3 ± 0.08 mAh/g, specific capacitance of 1179 ± 0.10 F g⁻¹ at 0.5 A g⁻¹, and outstanding cycling stability of 98% after 25,000 cycles compared to the other electrode materials. The porous and hollow structure, along with a large surface area, contributed to the enhanced electrochemical properties of the composite material. An HSC was constructed using NM-CH/ZnO@Co₃O₄ CNCs as the cathode and activated porous carbon (APC) as the anode, resulting in a device with a specific energy of 33 ± 0.12 Wh kg⁻¹ and a power density of 19354 ± 0.07 W kg⁻¹. The use of Bi-MOF electrodes presents new avenues for the development of high-performance energy storage materials, with the potential for industrial energy storage application demonstrated though the successful powering of portable lightbulbs.