A3(U2O4)(Ge2O7) (A = Rb, Cs): Mixed-valence uranium(V,VI) germanates

Chia Hui Lin, Kwang Hwa Lii

研究成果: 雜誌貢獻期刊論文同行評審

65 引文 斯高帕斯(Scopus)

摘要

(Figure Presented) An unusual mix: The first mixed-valence uranium(V,VI) germanates are synthesized under hydrothermal conditions. The structure of A3(U2O4)(Ge2O7) (A = Rb, Cs) contains chains of corner-sharing U5+O6 octahedra (purple) and U6+O6 tetragonal bipyramids (yellow), which are interconnected by GeO4 tetrahedra (green) to form a 3D framework (see picture; A blue).

原文???core.languages.en_GB???
頁(從 - 到)8711-8713
頁數3
期刊Angewandte Chemie - International Edition
47
發行號45
DOIs
出版狀態已出版 - 27 10月 2008

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