TY - JOUR
T1 - A new Mo5+ phosphate with a tunnel structure
T2 - γ-CsMo2P3O13
AU - Chen, J. J.
AU - Lii, K. H.
AU - Wang, S. L.
N1 - Funding Information:
The authors thank the National Science Council of the Republic of China for financial support of this study. K. H. Lii also expresses thanks for support from the Institute of Chemistry Academia Sinica.
PY - 1988/9
Y1 - 1988/9
N2 - A new Mo5+ phosphate, γ-CsMo2P3O13, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. γ-CsMo2P3O13 crystallizes in the triclinic space group P1 with a = 6.342(1), b = 9.676(1), c = 10.0349(8) Å, α = 83.083(7), β = 97.42(1), γ = 108.30(1)°, V = 577.7(2) Å3, Z = 2, R = 0.034, Rw = 0.042 for 2927 independent reflections with I > 2.5 σ(I). The structure consists of three different tunnels of which the large and medium ones are occupied by cesium cations. The framework is built up from MoO6 octahedra, PO4 tetrahedra, and P2O7 groups. The γ-CsMo2P3O13 structure is closely related to that of the β-form.
AB - A new Mo5+ phosphate, γ-CsMo2P3O13, was discovered and its crystal structure was determined from single-crystal X-ray diffraction data. γ-CsMo2P3O13 crystallizes in the triclinic space group P1 with a = 6.342(1), b = 9.676(1), c = 10.0349(8) Å, α = 83.083(7), β = 97.42(1), γ = 108.30(1)°, V = 577.7(2) Å3, Z = 2, R = 0.034, Rw = 0.042 for 2927 independent reflections with I > 2.5 σ(I). The structure consists of three different tunnels of which the large and medium ones are occupied by cesium cations. The framework is built up from MoO6 octahedra, PO4 tetrahedra, and P2O7 groups. The γ-CsMo2P3O13 structure is closely related to that of the β-form.
UR - http://www.scopus.com/inward/record.url?scp=0024072650&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(88)90208-3
DO - 10.1016/0022-4596(88)90208-3
M3 - 期刊論文
AN - SCOPUS:0024072650
VL - 76
SP - 204
EP - 209
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1
ER -