TY - JOUR
T1 - A new mixed-valence molybdenum phosphate with a tunnel structure
T2 - Cs3Mo6P10O38
AU - Lii, K. H.
AU - Wang, C. C.
PY - 1988/11
Y1 - 1988/11
N2 - The crystal structure of Cs3Mo6P10O38 has been determined from single-crystal X-ray diffraction data. It crystallizes in the triclinic space group P1 with a = 9.511(3), b = 14.232(4), c = 6.437(5), Å, α = 91.15(5), β = 105.92(5), γ = 90.04(2)°, V = 838(1), Å3, Z = 1, R = 0.057, Rw = 0.066, GOF = 1.97 for 1460 reflections with I > 2.5 σ(I). The structure contains several different types of tunnels of which two are occupied by Cs+. The structural formula is Cs3(Mo)2(Mo2O)2(PO4)2(P2O7)4. It is a mixed-valence molybdenum phosphate in which Mo3+ and Mo4+ are simultaneously present. The structural relationship between the title compound and Cs4Mo8P12O52 is discussed.
AB - The crystal structure of Cs3Mo6P10O38 has been determined from single-crystal X-ray diffraction data. It crystallizes in the triclinic space group P1 with a = 9.511(3), b = 14.232(4), c = 6.437(5), Å, α = 91.15(5), β = 105.92(5), γ = 90.04(2)°, V = 838(1), Å3, Z = 1, R = 0.057, Rw = 0.066, GOF = 1.97 for 1460 reflections with I > 2.5 σ(I). The structure contains several different types of tunnels of which two are occupied by Cs+. The structural formula is Cs3(Mo)2(Mo2O)2(PO4)2(P2O7)4. It is a mixed-valence molybdenum phosphate in which Mo3+ and Mo4+ are simultaneously present. The structural relationship between the title compound and Cs4Mo8P12O52 is discussed.
UR - http://www.scopus.com/inward/record.url?scp=0024107831&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(88)90098-9
DO - 10.1016/0022-4596(88)90098-9
M3 - 期刊論文
AN - SCOPUS:0024107831
VL - 77
SP - 117
EP - 123
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1
ER -