Zinc germanates incorporating organic amine ligands: Solvothermal synthesis and structural characterization of Zn2Ge4O 10(NH2CH2CH2CH2NH 2) and ZnGe2O5(NH2CH 2CH2NH2)

Chih Min Wang; Chia Hui Lin; Ciao Wei Yang; Kwang Hwa Lii

doi:10.1021/ic1004825

Zinc germanates incorporating organic amine ligands: Solvothermal synthesis and structural characterization of Zn₂Ge₄O ₁₀(NH₂CH₂CH₂CH₂NH ₂) and ZnGe₂O₅(NH₂CH ₂CH₂NH₂)

Chih Min Wang, Chia Hui Lin, Ciao Wei Yang, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO₄N trigonal bipyramids and unbranched vierer single layers with the composition [Ge₄O₁₀] and discrete ZnO ₂N₂ tetrahedra and unbranched zweier double chains with the composition [Ge₂O₅], respectively.

Original language	English
Pages (from-to)	5783-5785
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	13
DOIs	https://doi.org/10.1021/ic1004825
State	Published - 5 Jul 2010

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10.1021/ic1004825

CCDC 788990: Experimental Crystal Structure Determination
Wang, C.-M. (Creator), Lin, C.-H. (Creator), Yang, C.-W. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2011
DOI: 10.5517/ccvh09m, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccvh09m&sid=DataCite
Dataset
CCDC 788991: Experimental Crystal Structure Determination
Wang, C.-M. (Creator), Lin, C.-H. (Creator), Yang, C.-W. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2011
DOI: 10.5517/ccvh0bn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccvh0bn&sid=DataCite
Dataset

Cite this

@article{ec20c73b8a9e43b88f473732e7713a87,

title = "Zinc germanates incorporating organic amine ligands: Solvothermal synthesis and structural characterization of Zn2Ge4O 10(NH2CH2CH2CH2NH 2) and ZnGe2O5(NH2CH 2CH2NH2)",

abstract = "Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO4N trigonal bipyramids and unbranched vierer single layers with the composition [Ge4O10] and discrete ZnO 2N2 tetrahedra and unbranched zweier double chains with the composition [Ge2O5], respectively.",

author = "Wang, {Chih Min} and Lin, {Chia Hui} and Yang, {Ciao Wei} and Lii, {Kwang Hwa}",

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T1 - Zinc germanates incorporating organic amine ligands

T2 - Solvothermal synthesis and structural characterization of Zn2Ge4O 10(NH2CH2CH2CH2NH 2) and ZnGe2O5(NH2CH 2CH2NH2)

AU - Wang, Chih Min

AU - Lin, Chia Hui

AU - Yang, Ciao Wei

AU - Lii, Kwang Hwa

PY - 2010/7/5

Y1 - 2010/7/5

N2 - Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO4N trigonal bipyramids and unbranched vierer single layers with the composition [Ge4O10] and discrete ZnO 2N2 tetrahedra and unbranched zweier double chains with the composition [Ge2O5], respectively.

AB - Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO4N trigonal bipyramids and unbranched vierer single layers with the composition [Ge4O10] and discrete ZnO 2N2 tetrahedra and unbranched zweier double chains with the composition [Ge2O5], respectively.

UR - http://www.scopus.com/inward/record.url?scp=77954131695&partnerID=8YFLogxK

U2 - 10.1021/ic1004825

DO - 10.1021/ic1004825

M3 - 期刊論文

C2 - 20518478

AN - SCOPUS:77954131695

SN - 0020-1669

VL - 49

SP - 5783

EP - 5785

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Zinc germanates incorporating organic amine ligands: Solvothermal synthesis and structural characterization of Zn2Ge4O 10(NH2CH2CH2CH2NH 2) and ZnGe2O5(NH2CH 2CH2NH2)

Abstract

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Datasets

CCDC 788990: Experimental Crystal Structure Determination

CCDC 788991: Experimental Crystal Structure Determination

Cite this

Zinc germanates incorporating organic amine ligands: Solvothermal synthesis and structural characterization of Zn₂Ge₄O ₁₀(NH₂CH₂CH₂CH₂NH ₂) and ZnGe₂O₅(NH₂CH ₂CH₂NH₂)