Zinc complex-based hole transporting material for perovskite solar cell applications

Yogesh S. Tingare; Ya Chun Hsu; Jyun Dai Lin; Chaochin Su; Wan Chun Wang; Sheng Han Wang; Shi Yun Lai; Zhi Ting Wu; Ja Hon Lin; Hsiou Hsuan Wang; Wen Ren Li

doi:10.1039/d4tc00688g

Zinc complex-based hole transporting material for perovskite solar cell applications

Yogesh S. Tingare, Ya Chun Hsu, Jyun Dai Lin, Chaochin Su, Wan Chun Wang, Sheng Han Wang, Shi Yun Lai, Zhi Ting Wu, Ja Hon Lin, Hsiou Hsuan Wang, Wen Ren Li

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Developing hole-transport materials (HTMs) with high hole mobility is critical for constructing efficient perovskite solar cells (PSCs). We present a design strategy for improving hole mobility and PSC performance using a stable zinc complex-based HTM BPZ23. Compared to its non-metal counterpart (BP21), the BPZ23 demonstrated a 59.42% increase in hole mobility, resulting in a good perovskite layer with reduced trap-assisted recombination. As a result, the power conversion efficiency of the fabricated inverted PSC using BPZ23 is up to 19.75%, which is one of the highest reported for any transition metal complex-based HTM employed in inverted PSC. This research demonstrates a simple and efficient method for increasing hole mobility in HTMs and improving the photovoltaic performance of PSCs.

Original language	English
Pages (from-to)	10145-10151
Number of pages	7
Journal	Journal of Materials Chemistry C
Volume	12
Issue number	27
DOIs	https://doi.org/10.1039/d4tc00688g
State	Published - 14 May 2024

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10.1039/d4tc00688g

CCDC 2267695: Experimental Crystal Structure Determination
Tingare, Y. S. (Contributor), Hsu, Y.-C. (Contributor), Lin, J.-D. (Contributor), Su, C. (Contributor), Wang, W.-C. (Contributor), Wang, S.-H. (Contributor), Lai, S.-Y. (Contributor), Wu, Z.-T. (Contributor), Lin, J.-H. (Contributor), Wang, H.-H. (Contributor) & Li, W.-R. (Contributor), Cambridge Crystallographic Data Centre, 2024
DOI: 10.5517/ccdc.csd.cc2g3qgs, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc2g3qgs&sid=DataCite
Dataset

Cite this

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title = "Zinc complex-based hole transporting material for perovskite solar cell applications",

abstract = "Developing hole-transport materials (HTMs) with high hole mobility is critical for constructing efficient perovskite solar cells (PSCs). We present a design strategy for improving hole mobility and PSC performance using a stable zinc complex-based HTM BPZ23. Compared to its non-metal counterpart (BP21), the BPZ23 demonstrated a 59.42% increase in hole mobility, resulting in a good perovskite layer with reduced trap-assisted recombination. As a result, the power conversion efficiency of the fabricated inverted PSC using BPZ23 is up to 19.75%, which is one of the highest reported for any transition metal complex-based HTM employed in inverted PSC. This research demonstrates a simple and efficient method for increasing hole mobility in HTMs and improving the photovoltaic performance of PSCs.",

author = "Tingare, {Yogesh S.} and Hsu, {Ya Chun} and Lin, {Jyun Dai} and Chaochin Su and Wang, {Wan Chun} and Wang, {Sheng Han} and Lai, {Shi Yun} and Wu, {Zhi Ting} and Lin, {Ja Hon} and Wang, {Hsiou Hsuan} and Li, {Wen Ren}",

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doi = "10.1039/d4tc00688g",

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T1 - Zinc complex-based hole transporting material for perovskite solar cell applications

AU - Tingare, Yogesh S.

AU - Hsu, Ya Chun

AU - Lin, Jyun Dai

AU - Su, Chaochin

AU - Wang, Wan Chun

AU - Wang, Sheng Han

AU - Lai, Shi Yun

AU - Wu, Zhi Ting

AU - Lin, Ja Hon

AU - Wang, Hsiou Hsuan

AU - Li, Wen Ren

PY - 2024/5/14

Y1 - 2024/5/14

N2 - Developing hole-transport materials (HTMs) with high hole mobility is critical for constructing efficient perovskite solar cells (PSCs). We present a design strategy for improving hole mobility and PSC performance using a stable zinc complex-based HTM BPZ23. Compared to its non-metal counterpart (BP21), the BPZ23 demonstrated a 59.42% increase in hole mobility, resulting in a good perovskite layer with reduced trap-assisted recombination. As a result, the power conversion efficiency of the fabricated inverted PSC using BPZ23 is up to 19.75%, which is one of the highest reported for any transition metal complex-based HTM employed in inverted PSC. This research demonstrates a simple and efficient method for increasing hole mobility in HTMs and improving the photovoltaic performance of PSCs.

AB - Developing hole-transport materials (HTMs) with high hole mobility is critical for constructing efficient perovskite solar cells (PSCs). We present a design strategy for improving hole mobility and PSC performance using a stable zinc complex-based HTM BPZ23. Compared to its non-metal counterpart (BP21), the BPZ23 demonstrated a 59.42% increase in hole mobility, resulting in a good perovskite layer with reduced trap-assisted recombination. As a result, the power conversion efficiency of the fabricated inverted PSC using BPZ23 is up to 19.75%, which is one of the highest reported for any transition metal complex-based HTM employed in inverted PSC. This research demonstrates a simple and efficient method for increasing hole mobility in HTMs and improving the photovoltaic performance of PSCs.

UR - http://www.scopus.com/inward/record.url?scp=85196718004&partnerID=8YFLogxK

U2 - 10.1039/d4tc00688g

DO - 10.1039/d4tc00688g

M3 - 期刊論文

AN - SCOPUS:85196718004

SN - 2050-7526

VL - 12

SP - 10145

EP - 10151

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 27

ER -

Zinc complex-based hole transporting material for perovskite solar cell applications

Abstract

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CCDC 2267695: Experimental Crystal Structure Determination

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