Toward quartz and cristobalite: Spontaneous resolution, structures, and characterization of chiral silica-mimetic silver(I)-organic materials

Tzuoo Tsair Luo; Yen Hsiang Liu; Chun Chieh Chan; Sheng Ming Huang; Bor Chen Change; Yi Long Lu; Gene Hsiang Lee; Shin Ming Peng; Ju Chun Wang; Kuang Lieh Lu

doi:10.1021/ic701412q

Toward quartz and cristobalite: Spontaneous resolution, structures, and characterization of chiral silica-mimetic silver(I)-organic materials

Tzuoo Tsair Luo, Yen Hsiang Liu, Chun Chieh Chan, Sheng Ming Huang, Bor Chen Change, Yi Long Lu, Gene Hsiang Lee, Shin Ming Peng, Ju Chun Wang, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

An α-quartz-mimetic chiral coordination network of [Ag(L ¹)(CF₃-SO₃)]_n (L¹ = 5,5′-bipyrimidine), after treatment with PF₆^- anions, undergoes a solution-state structural transformation toward [Ag-(L ¹)(PF₆)]_n with a cristobalite-mimetic chiral structures. This structural transformation is accompanied by substantial enhancement in the fluorescent intensity and in the second-harmonic-generation response. The results also demonstrate an effective design strategy based on the spontaneous resolution route for the preparation of chiral architectures.

Original language	English
Pages (from-to)	10044-10046
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	24
DOIs	https://doi.org/10.1021/ic701412q
State	Published - 26 Nov 2007

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10.1021/ic701412q

CCDC 222046: Experimental Crystal Structure Determination
Luo, T.-T. (Creator), Liu, Y.-H. (Creator), Chan, C.-C. (Creator), Huang, S.-M. (Creator), Change, B.-C. (Contributor), Lu, Y.-L. (Creator), Lee, G.-H. (Creator), Peng, S.-M. (Creator), Wang, J.-C. (Creator) & Lu, K.-L. (Creator), The Cambridge Structural Database, 2008
DOI: 10.5517/cc7g1sh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7g1sh&sid=DataCite
Dataset
CCDC 222045: Experimental Crystal Structure Determination
Luo, T.-T. (Creator), Liu, Y.-H. (Creator), Chan, C.-C. (Creator), Huang, S.-M. (Creator), Change, B.-C. (Contributor), Lu, Y.-L. (Creator), Lee, G.-H. (Creator), Peng, S.-M. (Creator), Wang, J.-C. (Creator) & Lu, K.-L. (Creator), The Cambridge Structural Database, 2008
DOI: 10.5517/cc7g1rg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7g1rg&sid=DataCite
Dataset

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@article{dc846340ff91456eab28a7ff4163d9ef,

title = "Toward quartz and cristobalite: Spontaneous resolution, structures, and characterization of chiral silica-mimetic silver(I)-organic materials",

abstract = "An α-quartz-mimetic chiral coordination network of [Ag(L 1)(CF3-SO3)]n (L1 = 5,5′-bipyrimidine), after treatment with PF6- anions, undergoes a solution-state structural transformation toward [Ag-(L 1)(PF6)]n with a cristobalite-mimetic chiral structures. This structural transformation is accompanied by substantial enhancement in the fluorescent intensity and in the second-harmonic-generation response. The results also demonstrate an effective design strategy based on the spontaneous resolution route for the preparation of chiral architectures.",

author = "Luo, {Tzuoo Tsair} and Liu, {Yen Hsiang} and Chan, {Chun Chieh} and Huang, {Sheng Ming} and Change, {Bor Chen} and Lu, {Yi Long} and Lee, {Gene Hsiang} and Peng, {Shin Ming} and Wang, {Ju Chun} and Lu, {Kuang Lieh}",

year = "2007",

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day = "26",

doi = "10.1021/ic701412q",

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volume = "46",

pages = "10044--10046",

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TY - JOUR

T1 - Toward quartz and cristobalite

T2 - Spontaneous resolution, structures, and characterization of chiral silica-mimetic silver(I)-organic materials

AU - Luo, Tzuoo Tsair

AU - Liu, Yen Hsiang

AU - Chan, Chun Chieh

AU - Huang, Sheng Ming

AU - Change, Bor Chen

AU - Lu, Yi Long

AU - Lee, Gene Hsiang

AU - Peng, Shin Ming

AU - Wang, Ju Chun

AU - Lu, Kuang Lieh

PY - 2007/11/26

Y1 - 2007/11/26

N2 - An α-quartz-mimetic chiral coordination network of [Ag(L 1)(CF3-SO3)]n (L1 = 5,5′-bipyrimidine), after treatment with PF6- anions, undergoes a solution-state structural transformation toward [Ag-(L 1)(PF6)]n with a cristobalite-mimetic chiral structures. This structural transformation is accompanied by substantial enhancement in the fluorescent intensity and in the second-harmonic-generation response. The results also demonstrate an effective design strategy based on the spontaneous resolution route for the preparation of chiral architectures.

AB - An α-quartz-mimetic chiral coordination network of [Ag(L 1)(CF3-SO3)]n (L1 = 5,5′-bipyrimidine), after treatment with PF6- anions, undergoes a solution-state structural transformation toward [Ag-(L 1)(PF6)]n with a cristobalite-mimetic chiral structures. This structural transformation is accompanied by substantial enhancement in the fluorescent intensity and in the second-harmonic-generation response. The results also demonstrate an effective design strategy based on the spontaneous resolution route for the preparation of chiral architectures.

UR - http://www.scopus.com/inward/record.url?scp=37249089718&partnerID=8YFLogxK

U2 - 10.1021/ic701412q

DO - 10.1021/ic701412q

M3 - 期刊論文

C2 - 17958359

AN - SCOPUS:37249089718

SN - 0020-1669

VL - 46

SP - 10044

EP - 10046

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Toward quartz and cristobalite: Spontaneous resolution, structures, and characterization of chiral silica-mimetic silver(I)-organic materials

Abstract

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CCDC 222046: Experimental Crystal Structure Determination

CCDC 222045: Experimental Crystal Structure Determination

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