The structure of CsV(MoO4)2

K. H. Lii, C. C. Wang, R. K. Chiang, S. L. Wang

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The crystal structure of CsV(MoO4)2 was determined from single-crystal X-ray diffraction data. It crystallizes in the trigonal space group P3m1 (No. 164) with a = 5.662(3), c = 7.976(2)Å, Z = 1. The structure contains layers of vanadium molybdate with the cesium cations between the layers. Each layer is built up from corner-sharing VO6 octahedra and MoO4 tetrahedra. The structural relationship between the title compound, KAl(SO4)2, KV(SO4)2, and a high-temperature form of Zr(MoO4)2 is discussed.

Original languageEnglish
Pages (from-to)144-148
Number of pages5
JournalJournal of Solid State Chemistry
Volume80
Issue number1
DOIs
StatePublished - May 1989

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