The structure of CsV(MoO4)2

K. H. Lii; C. C. Wang; R. K. Chiang; S. L. Wang

doi:10.1016/0022-4596(89)90041-8

The structure of CsV(MoO₄)₂

K. H. Lii, C. C. Wang, R. K. Chiang, S. L. Wang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The crystal structure of CsV(MoO₄)₂ was determined from single-crystal X-ray diffraction data. It crystallizes in the trigonal space group P3m1 (No. 164) with a = 5.662(3), c = 7.976(2)Å, Z = 1. The structure contains layers of vanadium molybdate with the cesium cations between the layers. Each layer is built up from corner-sharing VO₆ octahedra and MoO₄ tetrahedra. The structural relationship between the title compound, KAl(SO₄)₂, KV(SO₄)₂, and a high-temperature form of Zr(MoO₄)₂ is discussed.

Original language	English
Pages (from-to)	144-148
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	80
Issue number	1
DOIs	https://doi.org/10.1016/0022-4596(89)90041-8
State	Published - May 1989

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title = "The structure of CsV(MoO4)2",

abstract = "The crystal structure of CsV(MoO4)2 was determined from single-crystal X-ray diffraction data. It crystallizes in the trigonal space group P3m1 (No. 164) with a = 5.662(3), c = 7.976(2){\AA}, Z = 1. The structure contains layers of vanadium molybdate with the cesium cations between the layers. Each layer is built up from corner-sharing VO6 octahedra and MoO4 tetrahedra. The structural relationship between the title compound, KAl(SO4)2, KV(SO4)2, and a high-temperature form of Zr(MoO4)2 is discussed.",

author = "Lii, {K. H.} and Wang, {C. C.} and Chiang, {R. K.} and Wang, {S. L.}",

note = "Funding Information: Support for this study by the National Science Council and the Institute of Chemistry Academia Sinica are gratefully acknowledged.",

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T1 - The structure of CsV(MoO4)2

AU - Lii, K. H.

AU - Wang, C. C.

AU - Chiang, R. K.

AU - Wang, S. L.

N1 - Funding Information: Support for this study by the National Science Council and the Institute of Chemistry Academia Sinica are gratefully acknowledged.

PY - 1989/5

Y1 - 1989/5

N2 - The crystal structure of CsV(MoO4)2 was determined from single-crystal X-ray diffraction data. It crystallizes in the trigonal space group P3m1 (No. 164) with a = 5.662(3), c = 7.976(2)Å, Z = 1. The structure contains layers of vanadium molybdate with the cesium cations between the layers. Each layer is built up from corner-sharing VO6 octahedra and MoO4 tetrahedra. The structural relationship between the title compound, KAl(SO4)2, KV(SO4)2, and a high-temperature form of Zr(MoO4)2 is discussed.

AB - The crystal structure of CsV(MoO4)2 was determined from single-crystal X-ray diffraction data. It crystallizes in the trigonal space group P3m1 (No. 164) with a = 5.662(3), c = 7.976(2)Å, Z = 1. The structure contains layers of vanadium molybdate with the cesium cations between the layers. Each layer is built up from corner-sharing VO6 octahedra and MoO4 tetrahedra. The structural relationship between the title compound, KAl(SO4)2, KV(SO4)2, and a high-temperature form of Zr(MoO4)2 is discussed.

UR - http://www.scopus.com/inward/record.url?scp=0042782559&partnerID=8YFLogxK

U2 - 10.1016/0022-4596(89)90041-8

DO - 10.1016/0022-4596(89)90041-8

M3 - 期刊論文

AN - SCOPUS:0042782559

VL - 80

SP - 144

EP - 148

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

IS - 1

ER -

The structure of CsV(MoO4)2

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The structure of CsV(MoO₄)₂