The influence of titanium on the properties of zinc oxide films deposited by radio frequency magnetron sputtering

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Abstract

TiO 2 -doped zinc oxide thin films were deposited on glass substrates by radio frequency (RF) magnetron sputtering with TiO 2 -doped ZnO targets in an argon atmosphere. The structural properties of TiO 2 -doped ZnO films doped with different TiO 2 contents were investigated. The experimental results show that polycrystalline TiO 2 -doped ZnO films had the (0 0 2) preferred orientation. The deposition parameters such as the working pressure and substrate temperature of TiO 2 -doped ZnO films were also investigated. The crystalline structure of the TiO 2 -doped ZnO films gradually improved as the working pressure was lowered and the substrate temperature was raised. The lowest electrical resistivity for the TiO 2 -doped ZnO films was obtained when the Ti addition was 1.34 wt%; its value was 2.50 × 10 -3 Ω cm, smaller than that found in previous studies. The transmittance of the TiO 2 -doped ZnO films in the visible wavelength range was more than 80%. The optical energy gap was related to the carrier concentration, and was in the range of 3.30-3.48 eV.

Original languageEnglish
Pages (from-to)2615-2620
Number of pages6
JournalApplied Surface Science
Volume254
Issue number9
DOIs
StatePublished - 28 Feb 2008

Keywords

  • Optical energy gap
  • Resistivity
  • Sputtering
  • Zinc oxide

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