The determination of zeolite crystal diffusivity by gas chromatography-II. Experimental

A. S. Chiang; A. G. Dixon; Y. H. Ma

doi:10.1016/0009-2509(84)80004-4

The determination of zeolite crystal diffusivity by gas chromatography-II. Experimental

A. S. Chiang, A. G. Dixon, Y. H. Ma

Department of Chemical and Materials Engineering

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Abstract

Experimental results are reported for the adsorption of propane and n-butane in a column packed with Linde 5A zeolite crystals, and methane, propan n- and iso-butane in a column packed with silicalite crystals. The adsorption equilibrium constant K and crystal diffusivity D_c, we obtained at different temperatures in the range 100-300°C, for each sorbate and packing and the heat of adsorption and diffusional activation energ were determined. The results show that in order to separate the effects of K and the pressure drop, the latter must be independently estimated by a suitable correla.

Original language	English
Pages (from-to)	1461-1468
Number of pages	8
Journal	Chemical Engineering Science
Volume	39
Issue number	10
DOIs	https://doi.org/10.1016/0009-2509(84)80004-4
State	Published - 1984

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abstract = "Experimental results are reported for the adsorption of propane and n-butane in a column packed with Linde 5A zeolite crystals, and methane, propan n- and iso-butane in a column packed with silicalite crystals. The adsorption equilibrium constant K and crystal diffusivity Dc, we obtained at different temperatures in the range 100-300°C, for each sorbate and packing and the heat of adsorption and diffusional activation energ were determined. The results show that in order to separate the effects of K and the pressure drop, the latter must be independently estimated by a suitable correla.",

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T1 - The determination of zeolite crystal diffusivity by gas chromatography-II. Experimental

AU - Chiang, A. S.

AU - Dixon, A. G.

AU - Ma, Y. H.

PY - 1984

Y1 - 1984

N2 - Experimental results are reported for the adsorption of propane and n-butane in a column packed with Linde 5A zeolite crystals, and methane, propan n- and iso-butane in a column packed with silicalite crystals. The adsorption equilibrium constant K and crystal diffusivity Dc, we obtained at different temperatures in the range 100-300°C, for each sorbate and packing and the heat of adsorption and diffusional activation energ were determined. The results show that in order to separate the effects of K and the pressure drop, the latter must be independently estimated by a suitable correla.

AB - Experimental results are reported for the adsorption of propane and n-butane in a column packed with Linde 5A zeolite crystals, and methane, propan n- and iso-butane in a column packed with silicalite crystals. The adsorption equilibrium constant K and crystal diffusivity Dc, we obtained at different temperatures in the range 100-300°C, for each sorbate and packing and the heat of adsorption and diffusional activation energ were determined. The results show that in order to separate the effects of K and the pressure drop, the latter must be independently estimated by a suitable correla.

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U2 - 10.1016/0009-2509(84)80004-4

DO - 10.1016/0009-2509(84)80004-4

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JO - Chemical Engineering Science

JF - Chemical Engineering Science

SN - 0009-2509

IS - 10

ER -

The determination of zeolite crystal diffusivity by gas chromatography-II. Experimental

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