The C3-bending levels of the C3-Ar complex studied by optical spectroscopy and ab initio calculation

Guiqiu Zhang; B. G. Lin; S. M. Wen; Yen Chu Hsu

doi:10.1063/1.1641017

The C₃-bending levels of the C₃-Ar complex studied by optical spectroscopy and ab initio calculation

Guiqiu Zhang, B. G. Lin, S. M. Wen, Yen Chu Hsu

Department of Physics

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The C₃-bending levels of the C₃-Ar complex were analyzed by laser-induced fluorescence and wavelength-resolved emission techniques. The ground state levels shifted progressively downwards compared to those of free C₃, with increasing bending excitation. The shift indicated that the van der Waals complexes are becoming more tightly bound. The level structure of the two vibrations of C₃-Ar was fitted to a perturbed harmonic oscillator model.

Original language	English
Pages (from-to)	3189-3200
Number of pages	12
Journal	Journal of Chemical Physics
Volume	120
Issue number	7
DOIs	https://doi.org/10.1063/1.1641017
State	Published - 15 Feb 2004

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10.1063/1.1641017

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abstract = "The C3-bending levels of the C3-Ar complex were analyzed by laser-induced fluorescence and wavelength-resolved emission techniques. The ground state levels shifted progressively downwards compared to those of free C3, with increasing bending excitation. The shift indicated that the van der Waals complexes are becoming more tightly bound. The level structure of the two vibrations of C3-Ar was fitted to a perturbed harmonic oscillator model.",

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AU - Lin, B. G.

AU - Wen, S. M.

AU - Hsu, Yen Chu

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Y1 - 2004/2/15

N2 - The C3-bending levels of the C3-Ar complex were analyzed by laser-induced fluorescence and wavelength-resolved emission techniques. The ground state levels shifted progressively downwards compared to those of free C3, with increasing bending excitation. The shift indicated that the van der Waals complexes are becoming more tightly bound. The level structure of the two vibrations of C3-Ar was fitted to a perturbed harmonic oscillator model.

AB - The C3-bending levels of the C3-Ar complex were analyzed by laser-induced fluorescence and wavelength-resolved emission techniques. The ground state levels shifted progressively downwards compared to those of free C3, with increasing bending excitation. The shift indicated that the van der Waals complexes are becoming more tightly bound. The level structure of the two vibrations of C3-Ar was fitted to a perturbed harmonic oscillator model.

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The C3-bending levels of the C3-Ar complex studied by optical spectroscopy and ab initio calculation

Abstract

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The C₃-bending levels of the C₃-Ar complex studied by optical spectroscopy and ab initio calculation