Synthesis of novel organic-inorganic hybrid compounds: Lanthanide phosphites incorporating a squarate ligand

Chih Min Wang, Kwang Hwa Lii

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The first examples of metal phosphite incorporating a squarate anion as a ligand have been synthesized by a hydrothermal method. Their structures contain zigzag chains of edge-sharing LnO8 (Ln = Sm, Eu, and Gd) square antiprisms connected by phosphite groups to form 2D layers, which are pillared by squarate ligands into a 3D framework. The photoluminescence properties of the Eu compound have also been studied.

Original languageEnglish
Pages (from-to)6335-6337
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number14
DOIs
StatePublished - 20 Jul 2009

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