The first examples of metal phosphite incorporating a squarate anion as a ligand have been synthesized by a hydrothermal method. Their structures contain zigzag chains of edge-sharing LnO8 (Ln = Sm, Eu, and Gd) square antiprisms connected by phosphite groups to form 2D layers, which are pillared by squarate ligands into a 3D framework. The photoluminescence properties of the Eu compound have also been studied.
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Lii, K. (Contributor) & Wang, C. (Contributor), The Cambridge Structural Database, 1 Jan 2009
Wang, C. (Contributor) & Lii, K. (Contributor), The Cambridge Structural Database, 1 Jan 2009