Abstract
The first examples of metal phosphite incorporating a squarate anion as a ligand have been synthesized by a hydrothermal method. Their structures contain zigzag chains of edge-sharing LnO8 (Ln = Sm, Eu, and Gd) square antiprisms connected by phosphite groups to form 2D layers, which are pillared by squarate ligands into a 3D framework. The photoluminescence properties of the Eu compound have also been studied.
| Original language | English |
|---|---|
| Pages (from-to) | 6335-6337 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 48 |
| Issue number | 14 |
| DOIs | |
| State | Published - 20 Jul 2009 |
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CCDC 715789: Experimental Crystal Structure Determination
Wang, C.-M. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2009
DOI: 10.5517/ccs0tzk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccs0tzk&sid=DataCite
Dataset
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CCDC 715788: Experimental Crystal Structure Determination
Wang, C.-M. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2009
DOI: 10.5517/ccs0tyj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccs0tyj&sid=DataCite
Dataset