Synthesis, crystal structure and 71Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga5(OH)2(C10H9N2)(C2O4)(PO4)4]·2H2O

Ching Yeh Chen; Peter P. Chu; Kwang Hwa Lii

doi:10.1039/a903213d

Synthesis, crystal structure and ⁷¹Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga₅(OH)₂(C₁₀H₉N₂)(C₂O₄)(PO₄)₄]·2H₂O

Ching Yeh Chen, Peter P. Chu, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The synthesis and characterization of a novel three-dimensional gallium phosphatooxalate is described; the structure consists of GaO₄ tetrahedra and GaO₆ octahedra linked by phosphate and oxalate groups to form two-dimensional sheets between which are GaO₄N square pyramids, generating tunnels in which the monoprotonated 4,4'-bipyridine molecules reside; ⁷¹Ga MAS NMR confirms the presence of four-, five- and six-coordinate Ga atoms.

Original language	English
Pages (from-to)	1473-1474
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/a903213d
State	Published - 21 Aug 1999

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10.1039/a903213d

CCDC 133463: Experimental Crystal Structure Determination
Chen, C. (Creator), Chu, P. (Creator) & Lii, K. (Creator), The Cambridge Structural Database, 2000
DOI: 10.5517/cc4gw8q, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4gw8q&sid=DataCite
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title = "Synthesis, crystal structure and 71Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga5(OH)2(C10H9N2)(C2O4)(PO4)4]·2H2O",

abstract = "The synthesis and characterization of a novel three-dimensional gallium phosphatooxalate is described; the structure consists of GaO4 tetrahedra and GaO6 octahedra linked by phosphate and oxalate groups to form two-dimensional sheets between which are GaO4N square pyramids, generating tunnels in which the monoprotonated 4,4'-bipyridine molecules reside; 71Ga MAS NMR confirms the presence of four-, five- and six-coordinate Ga atoms.",

author = "Chen, {Ching Yeh} and Chu, {Peter P.} and Lii, {Kwang Hwa}",

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T1 - Synthesis, crystal structure and 71Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate

T2 - [Ga5(OH)2(C10H9N2)(C2O4)(PO4)4]·2H2O

AU - Chen, Ching Yeh

AU - Chu, Peter P.

AU - Lii, Kwang Hwa

PY - 1999/8/21

Y1 - 1999/8/21

N2 - The synthesis and characterization of a novel three-dimensional gallium phosphatooxalate is described; the structure consists of GaO4 tetrahedra and GaO6 octahedra linked by phosphate and oxalate groups to form two-dimensional sheets between which are GaO4N square pyramids, generating tunnels in which the monoprotonated 4,4'-bipyridine molecules reside; 71Ga MAS NMR confirms the presence of four-, five- and six-coordinate Ga atoms.

AB - The synthesis and characterization of a novel three-dimensional gallium phosphatooxalate is described; the structure consists of GaO4 tetrahedra and GaO6 octahedra linked by phosphate and oxalate groups to form two-dimensional sheets between which are GaO4N square pyramids, generating tunnels in which the monoprotonated 4,4'-bipyridine molecules reside; 71Ga MAS NMR confirms the presence of four-, five- and six-coordinate Ga atoms.

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U2 - 10.1039/a903213d

DO - 10.1039/a903213d

M3 - 期刊論文

AN - SCOPUS:0033592083

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Synthesis, crystal structure and 71Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga5(OH)2(C10H9N2)(C2O4)(PO4)4]·2H2O

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CCDC 133463: Experimental Crystal Structure Determination

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Synthesis, crystal structure and ⁷¹Ga MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga₅(OH)₂(C₁₀H₉N₂)(C₂O₄)(PO₄)₄]·2H₂O