Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)·2H2O

Chih Min Wang; Cheng Wei Chiu; Hsiu Mei Lin; Kwang Hwa Lii

doi:10.1016/j.jssc.2013.09.021

Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe₂O ₆(OH)₂(CH₃CH(NH₂)CH ₂NH₂)·2H₂O

Chih Min Wang, Cheng Wei Chiu, Hsiu Mei Lin, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new indium borogermanate incorporating an organic amine ligand, InBGe₂O₆(OH)₂(CH₃CH(NH ₂)CH₂NH₂)·2H₂O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In ₂O₆N₄ octahedral dimers, Ge₂O ₆(OH) double tetrahedra, and BO₃(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm.

Original language	English
Pages (from-to)	116-119
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	208
DOIs	https://doi.org/10.1016/j.jssc.2013.09.021
State	Published - 2013

Keywords

Borogermanate
Crystal
Germanate
Indium
Solvothermal synthesis

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10.1016/j.jssc.2013.09.021

Cite this

@article{76ea92ba5ee34a548c4db1153b6a90bd,

title = "Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand: InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)·2H2O",

abstract = "A new indium borogermanate incorporating an organic amine ligand, InBGe2O6(OH)2(CH3CH(NH 2)CH2NH2)·2H2O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In 2O6N4 octahedral dimers, Ge2O 6(OH) double tetrahedra, and BO3(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm.",

keywords = "Borogermanate, Crystal, Germanate, Indium, Solvothermal synthesis",

author = "Wang, {Chih Min} and Chiu, {Cheng Wei} and Lin, {Hsiu Mei} and Lii, {Kwang Hwa}",

year = "2013",

doi = "10.1016/j.jssc.2013.09.021",

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volume = "208",

pages = "116--119",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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TY - JOUR

T1 - Synthesis, characterization, and properties of the first indium borogermanate incorporating an organic amine ligand

T2 - InBGe2O 6(OH)2(CH3CH(NH2)CH 2NH2)·2H2O

AU - Wang, Chih Min

AU - Chiu, Cheng Wei

AU - Lin, Hsiu Mei

AU - Lii, Kwang Hwa

PY - 2013

Y1 - 2013

N2 - A new indium borogermanate incorporating an organic amine ligand, InBGe2O6(OH)2(CH3CH(NH 2)CH2NH2)·2H2O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In 2O6N4 octahedral dimers, Ge2O 6(OH) double tetrahedra, and BO3(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm.

AB - A new indium borogermanate incorporating an organic amine ligand, InBGe2O6(OH)2(CH3CH(NH 2)CH2NH2)·2H2O, was synthesized under solvothermal conditions and characterized by infrared spectroscopy, thermogravimetric analysis, and emission spectroscopy. This compound is a new example of the combination of metal, boron, and germanium atoms into one structure in the presence of organic amine molecules. Its 2D sheets with one 3-, one 4-, and two types of 6-membered rings consist of In 2O6N4 octahedral dimers, Ge2O 6(OH) double tetrahedra, and BO3(OH) groups that are interconnected by water molecules to form a 3D supramolecular framework. Interestingly, the emission spectrum for this compound displays a strong broad band centered at 455 nm.

KW - Borogermanate

KW - Crystal

KW - Germanate

KW - Indium

KW - Solvothermal synthesis

UR - http://www.scopus.com/inward/record.url?scp=84886743048&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2013.09.021

DO - 10.1016/j.jssc.2013.09.021

M3 - 期刊論文

AN - SCOPUS:84886743048

SN - 0022-4596

VL - 208

SP - 116

EP - 119

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -