Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H4APPIP)[Ln3(C2O4) 5.5(H2PO2)2] 5H2O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine)

Chih Min Wang; Yi Ying Wu; Chia Hung Hou; Chii Chang Chen; Kwang Hwa Lii

doi:10.1021/ic801817e

Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H₄APPIP)[Ln₃(C₂O₄) _5.5(H₂PO₂)₂] 5H₂O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine)

Chih Min Wang, Yi Ying Wu, Chia Hung Hou, Chii Chang Chen, Kwang Hwa Lii

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Four isostructural organically templated lanthanide oxalatophosphates, (H₄APPIP) [Ln₃(C₂O₄)_5.5 (H₂PO₄)₂] 5H₂O (Ln = Er - Lu and APPIP = 1,4-bis(3-aminopropyl)piperazine), have been synthesized under hydrothermal conditions and characterized by single-crystal and powder X-ray diffraction. Their structures contain LnO₈ trigonal dodecahedra linked by three bis-bidentate oxalates to form layers in the (102) plane, which are connected by dihydrogen phosphate and bis-monodentate oxalate ligands to form a 3D framework. The charge-compensating tetraprotonated 1,4-bis-(3-aminopropyl)piperazinium cations and lattice water molecules are located in the 12-membered ring straight channels. They are the first examples of organically templated lanthanide oxalatophosphates. The thermal stability, guest desorption-sorption properties, variable-temperature in situ powder X-ray diffraction, magnetic susceptibility, and photoluminescence spectrum of the Er compound and catalytic activity of the Yb compound for the Biginelli reaction have also been studied.

Original language	English
Pages (from-to)	1519-1523
Number of pages	5
Journal	Inorganic Chemistry
Volume	48
Issue number	4
DOIs	https://doi.org/10.1021/ic801817e
State	Published - 16 Feb 2009

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CCDC 695763: Experimental Crystal Structure Determination
Wang, C.-M. (Contributor), Wu, Y.-Y. (Contributor), Hou, C.-H. (Contributor), Chen, C.-C. (Contributor) & Lii, K.-H. (Contributor), Cambridge Crystallographic Data Centre, 2009
DOI: 10.5517/ccrbzz0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrbzz0&sid=DataCite
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Wang, C. M., Wu, Y. Y., Hou, C. H., Chen, C. C., & Lii, K. H. (2009). Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H₄APPIP)[Ln₃(C₂O₄) _5.5(H₂PO₂)₂] 5H₂O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine). Inorganic Chemistry, 48(4), 1519-1523. https://doi.org/10.1021/ic801817e

@article{868f31a61ad94100881a8df091222264,

title = "Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H4APPIP)[Ln3(C2O4) 5.5(H2PO2)2] 5H2O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine)",

abstract = "Four isostructural organically templated lanthanide oxalatophosphates, (H4APPIP) [Ln3(C2O4)5.5 (H2PO4)2] 5H2O (Ln = Er - Lu and APPIP = 1,4-bis(3-aminopropyl)piperazine), have been synthesized under hydrothermal conditions and characterized by single-crystal and powder X-ray diffraction. Their structures contain LnO8 trigonal dodecahedra linked by three bis-bidentate oxalates to form layers in the (102) plane, which are connected by dihydrogen phosphate and bis-monodentate oxalate ligands to form a 3D framework. The charge-compensating tetraprotonated 1,4-bis-(3-aminopropyl)piperazinium cations and lattice water molecules are located in the 12-membered ring straight channels. They are the first examples of organically templated lanthanide oxalatophosphates. The thermal stability, guest desorption-sorption properties, variable-temperature in situ powder X-ray diffraction, magnetic susceptibility, and photoluminescence spectrum of the Er compound and catalytic activity of the Yb compound for the Biginelli reaction have also been studied.",

author = "Wang, {Chih Min} and Wu, {Yi Ying} and Hou, {Chia Hung} and Chen, {Chii Chang} and Lii, {Kwang Hwa}",

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Wang, CM, Wu, YY, Hou, CH, Chen, CC & Lii, KH 2009, 'Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H₄APPIP)[Ln₃(C₂O₄) _5.5(H₂PO₂)₂] 5H₂O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine)', Inorganic Chemistry, vol. 48, no. 4, pp. 1519-1523. https://doi.org/10.1021/ic801817e

Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure: (H₄APPIP)[Ln₃(C₂O₄) _5.5(H₂PO₂)₂] 5H₂O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine). / Wang, Chih Min; Wu, Yi Ying; Hou, Chia Hung et al.
In: Inorganic Chemistry, Vol. 48, No. 4, 16.02.2009, p. 1519-1523.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization, and properties of organically templated lanthanide oxalatophosphates with a three-dimensional honeycomb structure

T2 - (H4APPIP)[Ln3(C2O4) 5.5(H2PO2)2] 5H2O (Ln = Er - Lu, APPIA = 1,4-bis(3-aminopropyl)piperazine)

AU - Wang, Chih Min

AU - Wu, Yi Ying

AU - Hou, Chia Hung

AU - Chen, Chii Chang

AU - Lii, Kwang Hwa

PY - 2009/2/16

Y1 - 2009/2/16

N2 - Four isostructural organically templated lanthanide oxalatophosphates, (H4APPIP) [Ln3(C2O4)5.5 (H2PO4)2] 5H2O (Ln = Er - Lu and APPIP = 1,4-bis(3-aminopropyl)piperazine), have been synthesized under hydrothermal conditions and characterized by single-crystal and powder X-ray diffraction. Their structures contain LnO8 trigonal dodecahedra linked by three bis-bidentate oxalates to form layers in the (102) plane, which are connected by dihydrogen phosphate and bis-monodentate oxalate ligands to form a 3D framework. The charge-compensating tetraprotonated 1,4-bis-(3-aminopropyl)piperazinium cations and lattice water molecules are located in the 12-membered ring straight channels. They are the first examples of organically templated lanthanide oxalatophosphates. The thermal stability, guest desorption-sorption properties, variable-temperature in situ powder X-ray diffraction, magnetic susceptibility, and photoluminescence spectrum of the Er compound and catalytic activity of the Yb compound for the Biginelli reaction have also been studied.

AB - Four isostructural organically templated lanthanide oxalatophosphates, (H4APPIP) [Ln3(C2O4)5.5 (H2PO4)2] 5H2O (Ln = Er - Lu and APPIP = 1,4-bis(3-aminopropyl)piperazine), have been synthesized under hydrothermal conditions and characterized by single-crystal and powder X-ray diffraction. Their structures contain LnO8 trigonal dodecahedra linked by three bis-bidentate oxalates to form layers in the (102) plane, which are connected by dihydrogen phosphate and bis-monodentate oxalate ligands to form a 3D framework. The charge-compensating tetraprotonated 1,4-bis-(3-aminopropyl)piperazinium cations and lattice water molecules are located in the 12-membered ring straight channels. They are the first examples of organically templated lanthanide oxalatophosphates. The thermal stability, guest desorption-sorption properties, variable-temperature in situ powder X-ray diffraction, magnetic susceptibility, and photoluminescence spectrum of the Er compound and catalytic activity of the Yb compound for the Biginelli reaction have also been studied.

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U2 - 10.1021/ic801817e

DO - 10.1021/ic801817e

M3 - 期刊論文

C2 - 19159316

AN - SCOPUS:64349100441

SN - 0020-1669

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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