Synthesis and structure of (4,4′-H2bpy)[V2(HPO4)4 (4,4′-bpy)2], a novel two-dimensional network compound

C. H. Huang; L. H. Huang; K. H. Lii

doi:10.1021/ic001169g

Synthesis and structure of (4,4′-H₂bpy)[V₂(HPO₄)₄ (4,4′-bpy)₂], a novel two-dimensional network compound

C. H. Huang, L. H. Huang, K. H. Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

The synthesis and characterization of the first metal phosphate containing 4,4′-bipyridine in two distinct forms is described; the structure consist of phosphate-bridged vanadium(III) chains, which are linked through 4,4′-bipyridine ligands to form anionic {[V₂(HPO₄)₄-(4,4′-bpy)₂] ^2-}_∞ sheets with the charge-compensating uncoordinated (4,4′-H₂bpy)²⁺ cations between the sheets.

Original language	English
Pages (from-to)	2625-2627
Number of pages	3
Journal	Inorganic Chemistry
Volume	40
Issue number	11
DOIs	https://doi.org/10.1021/ic001169g
State	Published - 21 May 2001

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10.1021/ic001169g

CCDC 165556: Experimental Crystal Structure Determination
Huang, C.-H. (Creator), Huang, L.-H. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2001
DOI: 10.5517/cc5k8jh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc5k8jh&sid=DataCite
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abstract = "The synthesis and characterization of the first metal phosphate containing 4,4′-bipyridine in two distinct forms is described; the structure consist of phosphate-bridged vanadium(III) chains, which are linked through 4,4′-bipyridine ligands to form anionic \{[V2(HPO4)4-(4,4′-bpy)2] 2-\}∞ sheets with the charge-compensating uncoordinated (4,4′-H2bpy)2+ cations between the sheets.",

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AU - Huang, L. H.

AU - Lii, K. H.

PY - 2001/5/21

Y1 - 2001/5/21

N2 - The synthesis and characterization of the first metal phosphate containing 4,4′-bipyridine in two distinct forms is described; the structure consist of phosphate-bridged vanadium(III) chains, which are linked through 4,4′-bipyridine ligands to form anionic {[V2(HPO4)4-(4,4′-bpy)2] 2-}∞ sheets with the charge-compensating uncoordinated (4,4′-H2bpy)2+ cations between the sheets.

AB - The synthesis and characterization of the first metal phosphate containing 4,4′-bipyridine in two distinct forms is described; the structure consist of phosphate-bridged vanadium(III) chains, which are linked through 4,4′-bipyridine ligands to form anionic {[V2(HPO4)4-(4,4′-bpy)2] 2-}∞ sheets with the charge-compensating uncoordinated (4,4′-H2bpy)2+ cations between the sheets.

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M3 - 期刊論文

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Synthesis and structure of (4,4′-H2bpy)[V2(HPO4)4 (4,4′-bpy)2], a novel two-dimensional network compound

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CCDC 165556: Experimental Crystal Structure Determination

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Synthesis and structure of (4,4′-H₂bpy)[V₂(HPO₄)₄ (4,4′-bpy)₂], a novel two-dimensional network compound