Synthesis and structure of (4,4′-H2bpy)[V2(HPO4)4 (4,4′-bpy)2], a novel two-dimensional network compound

C. H. Huang, L. H. Huang, K. H. Lii

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Abstract

The synthesis and characterization of the first metal phosphate containing 4,4′-bipyridine in two distinct forms is described; the structure consist of phosphate-bridged vanadium(III) chains, which are linked through 4,4′-bipyridine ligands to form anionic {[V2(HPO4)4-(4,4′-bpy)2] 2-} sheets with the charge-compensating uncoordinated (4,4′-H2bpy)2+ cations between the sheets.

Original languageEnglish
Pages (from-to)2625-2627
Number of pages3
JournalInorganic Chemistry
Volume40
Issue number11
DOIs
StatePublished - 21 May 2001

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