Synthesis and characterization of the first organically templated metal oxalatophosphonate: (C3H12N2) 0.5[Ga3(C2O4)(CH3PO 3)4]·0.5H2O

Chia Hui Lin; Kwang Hwa Lii

doi:10.1021/ic049598s

Synthesis and characterization of the first organically templated metal oxalatophosphonate: (C₃H₁₂N₂) _0.5[Ga₃(C₂O₄)(CH₃PO ₃)₄]·0.5H₂O

Chia Hui Lin, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The first organically templated gallium oxalatophosphonate has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of GaO₆ octahedra and GaO₄ tetrahedra connected by methylphosphonate and bis-bidentate oxalate anions to form anionic sheets in the ab plane with the charge-compensating propylenediammonium cations and water molecules between the sheets. The methyl groups of the phosphonate ligands extend from both sides of the layers into the interlamellar region. Crystal data: monoclinic, space group P2₁/n (No. 14), a = 8.8514(4) Å, b = 16.3030(7) Å, c = 15.0816(7) Å, β = 97.539(1)°, and Z = 4.

Original language	English
Pages (from-to)	6403-6407
Number of pages	5
Journal	Inorganic Chemistry
Volume	43
Issue number	20
DOIs	https://doi.org/10.1021/ic049598s
State	Published - 4 Oct 2004

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10.1021/ic049598s

CCDC 254212: Experimental Crystal Structure Determination
Lii, K. (Contributor) & Lin, C. (Contributor), The Cambridge Structural Database, 1 Jan 2005
DOI: 10.5517/cc8jjdp, https://doi.org/10.5517%2Fcc8jjdp
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title = "Synthesis and characterization of the first organically templated metal oxalatophosphonate: (C3H12N2) 0.5[Ga3(C2O4)(CH3PO 3)4]·0.5H2O",

abstract = "The first organically templated gallium oxalatophosphonate has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of GaO6 octahedra and GaO4 tetrahedra connected by methylphosphonate and bis-bidentate oxalate anions to form anionic sheets in the ab plane with the charge-compensating propylenediammonium cations and water molecules between the sheets. The methyl groups of the phosphonate ligands extend from both sides of the layers into the interlamellar region. Crystal data: monoclinic, space group P21/n (No. 14), a = 8.8514(4) {\AA}, b = 16.3030(7) {\AA}, c = 15.0816(7) {\AA}, β = 97.539(1)°, and Z = 4.",

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T2 - (C3H12N2) 0.5[Ga3(C2O4)(CH3PO 3)4]·0.5H2O

AU - Lin, Chia Hui

AU - Lii, Kwang Hwa

PY - 2004/10/4

Y1 - 2004/10/4

N2 - The first organically templated gallium oxalatophosphonate has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of GaO6 octahedra and GaO4 tetrahedra connected by methylphosphonate and bis-bidentate oxalate anions to form anionic sheets in the ab plane with the charge-compensating propylenediammonium cations and water molecules between the sheets. The methyl groups of the phosphonate ligands extend from both sides of the layers into the interlamellar region. Crystal data: monoclinic, space group P21/n (No. 14), a = 8.8514(4) Å, b = 16.3030(7) Å, c = 15.0816(7) Å, β = 97.539(1)°, and Z = 4.

AB - The first organically templated gallium oxalatophosphonate has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis. The structure consists of GaO6 octahedra and GaO4 tetrahedra connected by methylphosphonate and bis-bidentate oxalate anions to form anionic sheets in the ab plane with the charge-compensating propylenediammonium cations and water molecules between the sheets. The methyl groups of the phosphonate ligands extend from both sides of the layers into the interlamellar region. Crystal data: monoclinic, space group P21/n (No. 14), a = 8.8514(4) Å, b = 16.3030(7) Å, c = 15.0816(7) Å, β = 97.539(1)°, and Z = 4.

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Synthesis and characterization of the first organically templated metal oxalatophosphonate: (C3H12N2) 0.5[Ga3(C2O4)(CH3PO 3)4]·0.5H2O

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CCDC 254212: Experimental Crystal Structure Determination

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Synthesis and characterization of the first organically templated metal oxalatophosphonate: (C₃H₁₂N₂) _0.5[Ga₃(C₂O₄)(CH₃PO ₃)₄]·0.5H₂O