TY - JOUR
T1 - Synthesis and characterization of new ferrocenylamine sulfide and selenide complexes
AU - Naiini, Ahmad A.
AU - Chung-Kung, Lai
AU - Brubaker, Carl H.
PY - 1989/6/15
Y1 - 1989/6/15
N2 - Some hitherto unknown ferrocenylamine sulfides and selenides, (η5-C5H4-SR)Fe(η5-C5H3-1-CH2NMe2- 2-SR) (R = Et, n-Pr, i-Pr, n-Bu, t-Bu, i-Pent),(R,S)(η5- C5H5)Fe(η5-C5H3-1-CH(Me)NMe2-2-SeR) (R = Ph, 4-Cl-Ph), (R,S)(η5-C5H4-SR)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent), (R,S)(η5-C5H4-SeMe)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SeMe), (S,R)(η5-C5H4-SR)Fe(η5-C5H3-1- CH(Me)NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent) and (S,R)(η5-C5H4-SeMe)Fe(η5-C5H3-1- CH(Me)NMe2-2-SeMe) have been synthesized via the lithiation of proper ferrocene precursors, followed by treatment with appropriate disulfides and diselenides. These compounds, which are air stable, have been characterized by 1H NMR, 13C NMR, IR, MS and elemental analysis.
AB - Some hitherto unknown ferrocenylamine sulfides and selenides, (η5-C5H4-SR)Fe(η5-C5H3-1-CH2NMe2- 2-SR) (R = Et, n-Pr, i-Pr, n-Bu, t-Bu, i-Pent),(R,S)(η5- C5H5)Fe(η5-C5H3-1-CH(Me)NMe2-2-SeR) (R = Ph, 4-Cl-Ph), (R,S)(η5-C5H4-SR)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent), (R,S)(η5-C5H4-SeMe)Fe(η5-C5H3-1-CH(Me)- NMe2-2-SeMe), (S,R)(η5-C5H4-SR)Fe(η5-C5H3-1- CH(Me)NMe2-2-SR) (R = Et, n-Pr, i-Pr, n-Bu, s-Bu, t-Bu, i-Pent) and (S,R)(η5-C5H4-SeMe)Fe(η5-C5H3-1- CH(Me)NMe2-2-SeMe) have been synthesized via the lithiation of proper ferrocene precursors, followed by treatment with appropriate disulfides and diselenides. These compounds, which are air stable, have been characterized by 1H NMR, 13C NMR, IR, MS and elemental analysis.
UR - http://www.scopus.com/inward/record.url?scp=45149142633&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)80593-9
DO - 10.1016/S0020-1693(00)80593-9
M3 - 期刊論文
AN - SCOPUS:45149142633
VL - 160
SP - 241
EP - 244
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 2
ER -