Syntheses and Structures of Organically Templated Iron Phosphates

Kwang Hwa Lii, Yuh Feng Huang, Vítezslav Zima, Chih Yuan Huang, Hsiu Mei Lin, Yau Chen Jiang, Fen Ling Liao, Sue Lein Wang

Research output: Contribution to journalReview articlepeer-review

219 Scopus citations

Abstract

Iron phosphates are of interest because of rich crystal chemistry and practical applications. New crystalline iron phosphates have been prepared in aqueous or predominantly nonaqueous solvents under mild hydrothermal conditions using organic amines as structure-directing agents. The effects of pH, solvent, and temperature on the reaction products are discussed. FePOs have been prepared with 1-D chain, 2-D layered, and 3-D open framework structures. An FePO containing a chiral amine is also synthesized. This review will summarize some of the results of the work in the area of organically templated iron phosphates.

Original languageEnglish
Pages (from-to)2599-2609
Number of pages11
JournalChemistry of Materials
Volume10
Issue number10
DOIs
StatePublished - Oct 1998

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