Studies on a novel safety-catch linker cleaved by Pummerer rearrangement

Chih Ho Tai, Hsiao Ching Wu, Wen Ren Li

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

(Equation Presented) We describe the use of a sulfide linkage as a safety-catch linker. This linker is significantly stable to acidic as well as basic conditions and allows transformations to be carried out on solid supports. Moreover, its cleavage is facile by applying Pummerer rearrangement after transforming it to sulfoxide.

Original languageEnglish
Pages (from-to)2905-2908
Number of pages4
JournalOrganic Letters
Volume6
Issue number17
DOIs
StatePublished - 19 Aug 2004

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