Structure alteration and activity improvement of PdCoAu/C catalysts for the oxygen reduction reaction

Yu Chen Wei, Kuan Wen Wang

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

In this study, the ternary catalysts in a form of Pd75Co 25-xAux/C (x = 5, 15 and 25 in at.%) are synthesized for the oxygen reduction reaction (ORR) through the deposition-precipitation method. The addition of Au in altering structures, surface conditions and electrochemical properties of PdCo catalysts are investigated by the combined exploration of XRD, TEM, cyclic voltammetry (CV) and linear sweep voltammetry (LSV) measurements. XRD results suggest that the incorporation of Au into Pd-Co contributes to the formation of inhomogeneous alloy structure. Regarding the surface condition, CV examination implies that the Pd-rich surface gradually changes to Pd, PdAu or PdCo alloy mixed surface species after Au modification. For the preparation of high effectively catalysts, it is suggested that the addition of Au can prominently promote the ORR activity owing to the presence of inhomogeneous alloys together with alloy mixed surface species.

Original languageEnglish
Title of host publicationPolymer Electrolyte Fuel Cells 11
PublisherElectrochemical Society Inc.
Pages2041-2047
Number of pages7
Edition1
ISBN (Electronic)9781607682547
ISBN (Print)9781607682547
DOIs
StatePublished - 2011
Event11th Polymer Electrolyte Fuel Cell Symposium, PEFC 11 - 220th ECS Meeting - Boston, MA, United States
Duration: 9 Oct 201114 Oct 2011

Publication series

NameECS Transactions
Number1
Volume41
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

Conference11th Polymer Electrolyte Fuel Cell Symposium, PEFC 11 - 220th ECS Meeting
Country/TerritoryUnited States
CityBoston, MA
Period9/10/1114/10/11

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