Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation

Hui Chong; Hsing An Lin; Mo Yuan Shen; Ching Yuan Liu; Haichao Zhao; Hsiao Hua Yu

doi:10.1021/acs.orglett.5b00875

Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation

Hui Chong, Hsing An Lin, Mo Yuan Shen, Ching Yuan Liu, Haichao Zhao, Hsiao Hua Yu

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Palladium-catalyzed direct C-H arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 °C) provide moderate to good yields (47%-72%) of products having potential applications in fluorescent bioimaging and organic optoelectronics. (Chemical Equation Presented).

Original language	English
Pages (from-to)	3198-3201
Number of pages	4
Journal	Organic Letters
Volume	17
Issue number	13
DOIs	https://doi.org/10.1021/acs.orglett.5b00875
State	Published - 2 Jul 2015

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title = "Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation",

abstract = "Palladium-catalyzed direct C-H arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 °C) provide moderate to good yields (47%-72%) of products having potential applications in fluorescent bioimaging and organic optoelectronics. (Chemical Equation Presented).",

author = "Hui Chong and Lin, {Hsing An} and Shen, {Mo Yuan} and Liu, {Ching Yuan} and Haichao Zhao and Yu, {Hsiao Hua}",

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T1 - Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation

AU - Chong, Hui

AU - Lin, Hsing An

AU - Shen, Mo Yuan

AU - Liu, Ching Yuan

AU - Zhao, Haichao

AU - Yu, Hsiao Hua

PY - 2015/7/2

Y1 - 2015/7/2

N2 - Palladium-catalyzed direct C-H arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 °C) provide moderate to good yields (47%-72%) of products having potential applications in fluorescent bioimaging and organic optoelectronics. (Chemical Equation Presented).

AB - Palladium-catalyzed direct C-H arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 °C) provide moderate to good yields (47%-72%) of products having potential applications in fluorescent bioimaging and organic optoelectronics. (Chemical Equation Presented).

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U2 - 10.1021/acs.orglett.5b00875

DO - 10.1021/acs.orglett.5b00875

M3 - 期刊論文

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JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Step-Economical Syntheses of Functional BODIPY-EDOT π-Conjugated Materials through Direct C-H Arylation

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