Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand: β-and γ-In2Ge 6O15(NH2CH2CH2NH 2)2

Chih Min Wang; Ciao Wei Yang; Chia Hui Lin; Kwang Hwa Lii

doi:10.1021/ic1017856

Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand: β-and γ-In₂Ge ₆O₁₅(NH₂CH₂CH₂NH ₂)₂

Chih Min Wang, Ciao Wei Yang, Chia Hui Lin, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two new polymorphs, β-and γ-In₂Ge₆O ₁₅(NH₂CH₂CH₂NH₂) ₂, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge₆O₁₅] that are connected by In ₂O₆N₄octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.

Original language	English
Pages (from-to)	10229-10231
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	22
DOIs	https://doi.org/10.1021/ic1017856
State	Published - 15 Nov 2010

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10.1021/ic1017856

CCDC 816213: Experimental Crystal Structure Determination
Wang, C.-M. (Creator), Yang, C.-W. (Creator), Lin, C.-H. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2011
DOI: 10.5517/ccwdbg1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwdbg1&sid=DataCite
Dataset
CCDC 816212: Experimental Crystal Structure Determination
Wang, C.-M. (Creator), Yang, C.-W. (Creator), Lin, C.-H. (Creator) & Lii, K.-H. (Creator), The Cambridge Structural Database, 2011
DOI: 10.5517/ccwdbf0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwdbf0&sid=DataCite
Dataset

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@article{be5983d63cf340db9badb694d916f74a,

title = "Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand: β-and γ-In2Ge 6O15(NH2CH2CH2NH 2)2",

abstract = "Two new polymorphs, β-and γ-In2Ge6O 15(NH2CH2CH2NH2) 2, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge6O15] that are connected by In 2O6N4octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.",

author = "Wang, {Chih Min} and Yang, {Ciao Wei} and Lin, {Chia Hui} and Lii, {Kwang Hwa}",

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T1 - Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand

T2 - β-and γ-In2Ge 6O15(NH2CH2CH2NH 2)2

AU - Wang, Chih Min

AU - Yang, Ciao Wei

AU - Lin, Chia Hui

AU - Lii, Kwang Hwa

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Two new polymorphs, β-and γ-In2Ge6O 15(NH2CH2CH2NH2) 2, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge6O15] that are connected by In 2O6N4octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.

AB - Two new polymorphs, β-and γ-In2Ge6O 15(NH2CH2CH2NH2) 2, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge6O15] that are connected by In 2O6N4octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.

UR - http://www.scopus.com/inward/record.url?scp=78149337498&partnerID=8YFLogxK

U2 - 10.1021/ic1017856

DO - 10.1021/ic1017856

M3 - 期刊論文

C2 - 20949953

AN - SCOPUS:78149337498

SN - 0020-1669

VL - 49

SP - 10229

EP - 10231

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand: β-and γ-In2Ge 6O15(NH2CH2CH2NH 2)2

Abstract

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CCDC 816213: Experimental Crystal Structure Determination

CCDC 816212: Experimental Crystal Structure Determination

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Solvothermal synthesis of two polymorphs of an indium germanate incorporating an organic amine ligand: β-and γ-In₂Ge ₆O₁₅(NH₂CH₂CH₂NH ₂)₂