Two new polymorphs, β-and γ-In2Ge6O 15(NH2CH2CH2NH2) 2, have been synthesized under solvothermal conditions using 2-methylpentamethylenediamine as a solvent and structurally characterized by single-crystal X-ray diffraction. Both structures contain single layers with the composition [Ge6O15] that are connected by In 2O6N4octahedral dimers to form 3D frameworks. The germanate layers contain four-, six-, and eight-membered rings and six-membered rings in the β and γ polymorphs, respectively. Compounds with related structures are discussed for comparison.
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Wang, C. (Contributor), Lin, C. (Contributor), Yang, C. (Contributor) & Lii, K. (Contributor), The Cambridge Structural Database, 1 Jan 2011
Lii, K. (Contributor), Lin, C. (Contributor), Wang, C. (Contributor) & Yang, C. (Contributor), The Cambridge Structural Database, 1 Jan 2011