Room temperature columnar 1,2,4-triazole core

Wen Ren Li, Jen Chun Su, Ying Chieh Ke, Chung K. Lai

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

A new type of five-membered heterocyclic 1,2,4-triazoles (1-5) with various substituents on the N-4 position, such as benzyl, phenyl or n-alkyl groups, utilized as core group to generate room temperature columnar mesophases is reported. The presence of lone pair electrons on the nitrogen atoms and/or nonplanarity in this type of heterocyclic structure might be responsible for the formation of the columnar mesophases and the resulting lower melting and clearing temperatures.

Original languageEnglish
Pages (from-to)1763-1765
Number of pages3
JournalJournal of Materials Chemistry
Volume11
Issue number7
DOIs
StatePublished - 2001

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