Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

Li Wei Lee, Ya Chuan Kao, Mei Ying Chung, Bor Chen Chang, Gene Hsiang Lee, Shie Ming Peng, Chih Min Wang, Yen Hsiang Liu, Sheng Long Lee, Kuang Lieh Lu

Research output: Contribution to journalArticlepeer-review

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Abstract

An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn 2 (4-abpt)(3,4-pydc) 2 ]·2DMAc·3MeOH·H 2 O} n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.

Original languageEnglish
Pages (from-to)1950-1954
Number of pages5
JournalDalton Transactions
Volume48
Issue number6
DOIs
StatePublished - 2019

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