Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

Li Wei Lee; Ya Chuan Kao; Mei Ying Chung; Bor Chen Chang; Gene Hsiang Lee; Shie Ming Peng; Chih Min Wang; Yen Hsiang Liu; Sheng Long Lee; Kuang Lieh Lu

doi:10.1039/c8dt04472d

Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

Li Wei Lee, Ya Chuan Kao, Mei Ying Chung, Bor Chen Chang, Gene Hsiang Lee, Shie Ming Peng, Chih Min Wang, Yen Hsiang Liu, Sheng Long Lee, Kuang Lieh Lu

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Abstract

An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn ₂ (4-abpt)(3,4-pydc) ₂ ]·2DMAc·3MeOH·H ₂ O} _n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn ^II ions with Cu ^II ions while retaining the integrity of the network.

Original language	English
Pages (from-to)	1950-1954
Number of pages	5
Journal	Dalton Transactions
Volume	48
Issue number	6
DOIs	https://doi.org/10.1039/c8dt04472d
State	Published - 2019

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10.1039/c8dt04472d

CCDC 1875752: Experimental Crystal Structure Determination
Lee, L. (Creator), Kao, Y. (Creator), Chung, M. (Creator), Chang, B. (Creator), Lee, G. (Creator), Peng, S. (Creator), Wang, C. (Creator), Liu, Y. (Creator), Lee, S. (Creator) & Lu, K. (Creator), The Cambridge Structural Database, 2019
DOI: 10.5517/ccdc.csd.cc20yw40, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc20yw40&sid=DataCite
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title = "Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF",

abstract = " An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn 2 (4-abpt)(3,4-pydc) 2 ]·2DMAc·3MeOH·H 2 O} n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.",

author = "Lee, {Li Wei} and Kao, {Ya Chuan} and Chung, {Mei Ying} and Chang, {Bor Chen} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and Wang, {Chih Min} and Liu, {Yen Hsiang} and Lee, {Sheng Long} and Lu, {Kuang Lieh}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8dt04472d",

language = "???core.languages.en_GB???",

volume = "48",

pages = "1950--1954",

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TY - JOUR

T1 - Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

AU - Lee, Li Wei

AU - Kao, Ya Chuan

AU - Chung, Mei Ying

AU - Chang, Bor Chen

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Wang, Chih Min

AU - Liu, Yen Hsiang

AU - Lee, Sheng Long

AU - Lu, Kuang Lieh

PY - 2019

Y1 - 2019

N2 - An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn 2 (4-abpt)(3,4-pydc) 2 ]·2DMAc·3MeOH·H 2 O} n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.

AB - An SHG-active noncentrosymmetric (3,4)-connected Zn(ii)-organic framework, {[Zn 2 (4-abpt)(3,4-pydc) 2 ]·2DMAc·3MeOH·H 2 O} n (1-Zn), was synthesized using a mixed-ligand system. The 1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.

UR - http://www.scopus.com/inward/record.url?scp=85061085810&partnerID=8YFLogxK

U2 - 10.1039/c8dt04472d

DO - 10.1039/c8dt04472d

M3 - 期刊論文

C2 - 30644928

AN - SCOPUS:85061085810

SN - 1477-9226

VL - 48

SP - 1950

EP - 1954

JO - Dalton Transactions

JF - Dalton Transactions

IS - 6

ER -

Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3,4)-connected 3D MOF

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CCDC 1875752: Experimental Crystal Structure Determination

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