PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE

S. W. Lee; W. Y. Huang; Y. C. Huang; C. J. Tseng

PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE

S. W. Lee, W. Y. Huang, Y. C. Huang, C. J. Tseng

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The electrochemical performances of the solid oxide fuel cells (SOFCs) fabricated with Nd-doped LSCF (NLSCF) perovskite cathodes, thin BCZY electrolytes, and BCZY-Ni anodes by tape casting, spin coating, and co-firing are evaluated at 600-800 ℃. Material analysis, such as SEM, TEM, and XRD, confirmed that no detectable second phase remains in the NLSCF cathode, indicating that the calcined NLSCF nanopowders have good compatibility with the fabrication of anode-supported fuel cells in this study. It can be clearly seen that the NLSCF cathode is highly porous and adhered well to the BCZY electrolyte. Fuel cell testing with the NLSCF cathode exhibits a maximum power density of ~407.6 mW/cm² at 800 ℃, which is significantly higher than those of cells with a powder-derived LSCF cathode. The significantly lower polarization resistance elements extracted from electrochemical impedance spectroscopy (EIS) further suggested that the NLSCF cathode has superior catalytic activity for the oxygen reduction reaction and better oxygen ionic transport in the cathode reactions. The performance improvement of NLSCF cathode can be explained in terms of trade-off between electrocatalytic activity, oxygen ionic and electronic conductivity of the NLSCF. This study shows that NLSCF nanopowder would be a promising cathode material for proton-conducting SOFCs.

Original language	English
Title of host publication	Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference
Subtitle of host publication	Bridging Continents by H2
Editors	Ibrahim Dincer, Can Ozgur Colpan, Mehmet Akif Ezan
Publisher	International Association for Hydrogen Energy, IAHE
Pages	1394-1396
Number of pages	3
ISBN (Electronic)	9786250008430
State	Published - 2022
Event	23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022 - Istanbul, Turkey Duration: 26 Jun 2022 → 30 Jun 2022

Publication series

Name	Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2

Conference

Conference	23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022
Country/Territory	Turkey
City	Istanbul
Period	26/06/22 → 30/06/22

Keywords

Cathode
Nanopowder
Nd-doped LSCF
Oxygen reduction reaction
P-SOFC

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Cite this

Lee, S. W., Huang, W. Y., Huang, Y. C., & Tseng, C. J. (2022). PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE. In I. Dincer, C. O. Colpan, & M. A. Ezan (Eds.), Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2 (pp. 1394-1396). (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2). International Association for Hydrogen Energy, IAHE.

Lee, S. W. ; Huang, W. Y. ; Huang, Y. C. et al. / PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE. Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. editor / Ibrahim Dincer ; Can Ozgur Colpan ; Mehmet Akif Ezan. International Association for Hydrogen Energy, IAHE, 2022. pp. 1394-1396 (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).

@inproceedings{d8d972ae413a4ec399b5be8048d67094,

title = "PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE",

abstract = "The electrochemical performances of the solid oxide fuel cells (SOFCs) fabricated with Nd-doped LSCF (NLSCF) perovskite cathodes, thin BCZY electrolytes, and BCZY-Ni anodes by tape casting, spin coating, and co-firing are evaluated at 600-800 ℃. Material analysis, such as SEM, TEM, and XRD, confirmed that no detectable second phase remains in the NLSCF cathode, indicating that the calcined NLSCF nanopowders have good compatibility with the fabrication of anode-supported fuel cells in this study. It can be clearly seen that the NLSCF cathode is highly porous and adhered well to the BCZY electrolyte. Fuel cell testing with the NLSCF cathode exhibits a maximum power density of ~407.6 mW/cm2 at 800 ℃, which is significantly higher than those of cells with a powder-derived LSCF cathode. The significantly lower polarization resistance elements extracted from electrochemical impedance spectroscopy (EIS) further suggested that the NLSCF cathode has superior catalytic activity for the oxygen reduction reaction and better oxygen ionic transport in the cathode reactions. The performance improvement of NLSCF cathode can be explained in terms of trade-off between electrocatalytic activity, oxygen ionic and electronic conductivity of the NLSCF. This study shows that NLSCF nanopowder would be a promising cathode material for proton-conducting SOFCs.",

keywords = "Cathode, Nanopowder, Nd-doped LSCF, Oxygen reduction reaction, P-SOFC",

author = "Lee, {S. W.} and Huang, {W. Y.} and Huang, {Y. C.} and Tseng, {C. J.}",

note = "Publisher Copyright: {\textcopyright} 2022 Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. All rights reserved.; 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022 ; Conference date: 26-06-2022 Through 30-06-2022",

year = "2022",

language = "???core.languages.en_GB???",

series = "Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2",

publisher = "International Association for Hydrogen Energy, IAHE",

pages = "1394--1396",

editor = "Ibrahim Dincer and Colpan, {Can Ozgur} and Ezan, {Mehmet Akif}",

booktitle = "Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference",

}

Lee, SW, Huang, WY, Huang, YC & Tseng, CJ 2022, PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE. in I Dincer, CO Colpan & MA Ezan (eds), Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2, International Association for Hydrogen Energy, IAHE, pp. 1394-1396, 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022, Istanbul, Turkey, 26/06/22.

PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE. / Lee, S. W.; Huang, W. Y.; Huang, Y. C. et al.
Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. ed. / Ibrahim Dincer; Can Ozgur Colpan; Mehmet Akif Ezan. International Association for Hydrogen Energy, IAHE, 2022. p. 1394-1396 (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE

AU - Lee, S. W.

AU - Huang, W. Y.

AU - Huang, Y. C.

AU - Tseng, C. J.

PY - 2022

Y1 - 2022

N2 - The electrochemical performances of the solid oxide fuel cells (SOFCs) fabricated with Nd-doped LSCF (NLSCF) perovskite cathodes, thin BCZY electrolytes, and BCZY-Ni anodes by tape casting, spin coating, and co-firing are evaluated at 600-800 ℃. Material analysis, such as SEM, TEM, and XRD, confirmed that no detectable second phase remains in the NLSCF cathode, indicating that the calcined NLSCF nanopowders have good compatibility with the fabrication of anode-supported fuel cells in this study. It can be clearly seen that the NLSCF cathode is highly porous and adhered well to the BCZY electrolyte. Fuel cell testing with the NLSCF cathode exhibits a maximum power density of ~407.6 mW/cm2 at 800 ℃, which is significantly higher than those of cells with a powder-derived LSCF cathode. The significantly lower polarization resistance elements extracted from electrochemical impedance spectroscopy (EIS) further suggested that the NLSCF cathode has superior catalytic activity for the oxygen reduction reaction and better oxygen ionic transport in the cathode reactions. The performance improvement of NLSCF cathode can be explained in terms of trade-off between electrocatalytic activity, oxygen ionic and electronic conductivity of the NLSCF. This study shows that NLSCF nanopowder would be a promising cathode material for proton-conducting SOFCs.

AB - The electrochemical performances of the solid oxide fuel cells (SOFCs) fabricated with Nd-doped LSCF (NLSCF) perovskite cathodes, thin BCZY electrolytes, and BCZY-Ni anodes by tape casting, spin coating, and co-firing are evaluated at 600-800 ℃. Material analysis, such as SEM, TEM, and XRD, confirmed that no detectable second phase remains in the NLSCF cathode, indicating that the calcined NLSCF nanopowders have good compatibility with the fabrication of anode-supported fuel cells in this study. It can be clearly seen that the NLSCF cathode is highly porous and adhered well to the BCZY electrolyte. Fuel cell testing with the NLSCF cathode exhibits a maximum power density of ~407.6 mW/cm2 at 800 ℃, which is significantly higher than those of cells with a powder-derived LSCF cathode. The significantly lower polarization resistance elements extracted from electrochemical impedance spectroscopy (EIS) further suggested that the NLSCF cathode has superior catalytic activity for the oxygen reduction reaction and better oxygen ionic transport in the cathode reactions. The performance improvement of NLSCF cathode can be explained in terms of trade-off between electrocatalytic activity, oxygen ionic and electronic conductivity of the NLSCF. This study shows that NLSCF nanopowder would be a promising cathode material for proton-conducting SOFCs.

KW - Cathode

KW - Nanopowder

KW - Nd-doped LSCF

KW - Oxygen reduction reaction

KW - P-SOFC

UR - http://www.scopus.com/inward/record.url?scp=85147193120&partnerID=8YFLogxK

M3 - 會議論文篇章

AN - SCOPUS:85147193120

T3 - Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2

SP - 1394

EP - 1396

BT - Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference

A2 - Dincer, Ibrahim

A2 - Colpan, Can Ozgur

A2 - Ezan, Mehmet Akif

PB - International Association for Hydrogen Energy, IAHE

T2 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022

Y2 - 26 June 2022 through 30 June 2022

ER -

Lee SW, Huang WY, Huang YC, Tseng CJ. PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE. In Dincer I, Colpan CO, Ezan MA, editors, Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. International Association for Hydrogen Energy, IAHE. 2022. p. 1394-1396. (Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2).

PROTON-CONDUCTING SOLID OXIDE FUEL CELLS WITH NLSCF CATHODE

Abstract

Publication series

Conference

Keywords

UN SDGs

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