Promoting formic acid oxidation performance of Pd nanoparticlesviaPt and Ru atom mediated surface engineering

Dinesh Bhalothia, Tzu Hsi Huang, Pai Hung Chou, Kuan Wen Wang, Tsan Yao Chen

Research output: Contribution to journalArticlepeer-review

15 Scopus citations


The alteration of surface functional propertiesviaincorporation of foreign atoms is supposed to be a key strategy for the enhanced catalytic performance of noble-metal based nanocatalysts (NCs). In the present study, carbon-supported palladium (Pd)-based NCs including Pd, PdPt and PdRuPt have been preparedviaa polyol reduction method under the same reduction conditions as for formic acid oxidation reaction (FAOR) applications. By cross-referencing the results of the microscopic, spectroscopic and electrochemical analysis we demonstrated that adding a small amount of platinum (Pt) into Pd NCs (i.e.PdPt NCs) significantly promotes the FAOR performance as compared to that of Pd NCsviaweakening the COadsbond strength at a lower voltage (0.875 Vvs.NHE) than Pd (0.891 Vvs.NHE). Of special relevance, the PdPt NC shows a mass activity (MA) of 1.0 A mg−1and 1.9 A mg−1, respectively, in the anodic and cathodic scan. These values are ∼1.7-fold (0.6 A mg−1) and ∼4.8-fold (0.4 A mg−1) higher than those of Pd NC. Moreover, PdPt NC retains a higher MA (54 mA mg−1) than that of Pd NC (9 mA mg−1) after chronoamperometric (CA) stability tests over 2000 s. Meanwhile, further addition of ruthenium (Ru) (i.e.PdRuPt NCs) outstandingly enhances the CO tolerance during the CA testviaremoval of adsorbed COadsand thus shows the highest MA (62 mA mg−1) after CA testing, which is higher than that of PdPt (54 mA mg−1) and Pd (9 mA mg−1) NCs. The intriguing results obtained in this study have great significance to provide further strategic opportunities for tuning the surface electronic properties of Pd-based NCs to design Pd-based NCs with improved electrochemical performance.

Original languageEnglish
Pages (from-to)17302-17310
Number of pages9
JournalRSC Advances
Issue number29
StatePublished - 5 May 2020


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