Practical preparation of 2-halomethyl-allyl carboxylates

Chong Si Sun, Hsiu Yi Cheng, Yu Shiang Lin, Duen Ren Hou

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

An improved, efficient preparation of 2-(halomethyl)allyl carboxylates starting from diethyl bis(hydroxymethyl) malonate and hydrobromic acid is reported. The allylic halogen of 2-(chloromethyl)acrylate and 2-(bromomethyl)acrylate are readily exchanged during esterification.

Original languageEnglish
Pages (from-to)435-438
Number of pages4
JournalJournal of the Chinese Chemical Society
Volume55
Issue number2
DOIs
StatePublished - 2008

Keywords

  • 1,3-bifunctional
  • 2-(halomethyl)allyl
  • Acrylate

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