Potential-selective fate of 2D chiral crystallization on an electrode surface

Chia Ho Wu; Sureshraju Vegiraju; Ming Chou Chen; Shakil N. Afraj; Bo Yuan Huang; Shuehlin Yau

doi:10.1039/c9cc04410h

Potential-selective fate of 2D chiral crystallization on an electrode surface

Chia Ho Wu, Sureshraju Vegiraju, Ming Chou Chen, Shakil N. Afraj, Bo Yuan Huang, Shuehlin Yau

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Molecular resolution STM is used to study the spatial structure and chirality of adsorbed Δ4,4-dicyclopenta[2,1-b:3,4-b]-dithiophene (TTE) on an Au(111) electrode, revealing an ordered, racemate adlayer made of homogeneously mixed R- and S-TTE on the (1 × 1) substrate and patches of R- or S-only TTE on the reconstructed Au(111) at more and less positive potentials.

Original language	English
Pages (from-to)	10116-10119
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	68
DOIs	https://doi.org/10.1039/c9cc04410h
State	Published - 2019

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10.1039/c9cc04410h

Improvement of Divalent Cations (Ca2+ and Mg2+) Empirical Force Field Parameters: Applications for Electrolyte and Negatively Charged Biomolecular Simulations(II)
Tsai, H.-H. (PI)
1/08/18 → 31/07/19
Project: Research

CCDC 1910955: Experimental Crystal Structure Determination
Wu, C. (Contributor), Vegiraju, S. (Contributor), Chen, M.-C. (Contributor), Afraj, S. N. (Contributor), Huang, B.-Y. (Contributor) & Yau, S. (Contributor), The Cambridge Structural Database, 2020
DOI: 10.5517/ccdc.csd.cc224hqg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc224hqg&sid=DataCite
Dataset

Cite this

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title = "Potential-selective fate of 2D chiral crystallization on an electrode surface",

abstract = "Molecular resolution STM is used to study the spatial structure and chirality of adsorbed Δ4,4-dicyclopenta[2,1-b:3,4-b]-dithiophene (TTE) on an Au(111) electrode, revealing an ordered, racemate adlayer made of homogeneously mixed R- and S-TTE on the (1 × 1) substrate and patches of R- or S-only TTE on the reconstructed Au(111) at more and less positive potentials.",

author = "Wu, {Chia Ho} and Sureshraju Vegiraju and Chen, {Ming Chou} and Afraj, {Shakil N.} and Huang, {Bo Yuan} and Shuehlin Yau",

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T1 - Potential-selective fate of 2D chiral crystallization on an electrode surface

AU - Wu, Chia Ho

AU - Vegiraju, Sureshraju

AU - Chen, Ming Chou

AU - Afraj, Shakil N.

AU - Huang, Bo Yuan

AU - Yau, Shuehlin

PY - 2019

Y1 - 2019

N2 - Molecular resolution STM is used to study the spatial structure and chirality of adsorbed Δ4,4-dicyclopenta[2,1-b:3,4-b]-dithiophene (TTE) on an Au(111) electrode, revealing an ordered, racemate adlayer made of homogeneously mixed R- and S-TTE on the (1 × 1) substrate and patches of R- or S-only TTE on the reconstructed Au(111) at more and less positive potentials.

AB - Molecular resolution STM is used to study the spatial structure and chirality of adsorbed Δ4,4-dicyclopenta[2,1-b:3,4-b]-dithiophene (TTE) on an Au(111) electrode, revealing an ordered, racemate adlayer made of homogeneously mixed R- and S-TTE on the (1 × 1) substrate and patches of R- or S-only TTE on the reconstructed Au(111) at more and less positive potentials.

UR - http://www.scopus.com/inward/record.url?scp=85071265491&partnerID=8YFLogxK

U2 - 10.1039/c9cc04410h

DO - 10.1039/c9cc04410h

M3 - 期刊論文

C2 - 31385576

AN - SCOPUS:85071265491

SN - 1359-7345

VL - 55

SP - 10116

EP - 10119

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Potential-selective fate of 2D chiral crystallization on an electrode surface

Abstract

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Projects

Improvement of Divalent Cations (Ca2+ and Mg2+) Empirical Force Field Parameters: Applications for Electrolyte and Negatively Charged Biomolecular Simulations(II)

Datasets

CCDC 1910955: Experimental Crystal Structure Determination

Cite this