TY - JOUR
T1 - Overview of the CPOC Pilot Study at Whiteface Mountain, NY Cloud Processing of Organics within Clouds (CPOC)
AU - Lance, Sara
AU - Zhang, Jie
AU - Schwab, James J.
AU - Casson, Paul
AU - Brandt, Richard E.
AU - Fitzjarrald, David R.
AU - Schwab, Margaret J.
AU - Sicker, John
AU - Lu, Cheng Hsuan
AU - Chen, Sheng Po
AU - Yun, Jeongran
AU - Freedman, Jeffrey M.
AU - Shrestha, Bhupal
AU - Min, Qilong
AU - Beauharnois, Mark
AU - Crandall, Brian
AU - Joseph, Everette
AU - Brewer, Matthew J.
AU - Minder, Justin R.
AU - Orlowski, Daniel
AU - Christiansen, Amy
AU - Carlton, Annmarie G.
AU - Barth, Mary C.
N1 - Publisher Copyright:
©2020 American Meteorological Society For information regarding reuse of this content and general copyright information, consult the AMS Copyright Policy.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - Aqueous chemical processing within cloud and fog water is thought to be a key process in the production and transformation of secondary organic aerosol mass, found abundantly and ubiquitously throughout the troposphere. Yet, significant uncertainty remains regarding the organic chemical reactions taking place within clouds and the conditions under which those reactions occur, owing to the wide variety of organic compounds and their evolution under highly variable conditions when cycled through clouds. Continuous observations from a fixed remote site like Whiteface Mountain (WFM) in New York State and other mountaintop sites have been used to unravel complex multiphase interactions in the past, particularly the conversion of gas-phase emissions of SO2 to sulfuric acid within cloud droplets in the presence of sunlight. These scientific insights led to successful control strategies that reduced aerosol sulfate and cloud water acidity substantially over the following decades. This paper provides an overview of observations obtained during a pilot study that took place at WFM in August 2017 aimed at obtaining a better understanding of Chemical Processing of Organic Compounds within Clouds (CPOC). During the CPOC pilot study, aerosol cloud activation efficiency, particle size distribution, and chemical composition measurements were obtained below-cloud for comparison to routine observations at WFM, including cloud water composition and reactive trace gases. Additional instruments deployed for the CPOC pilot study included a Doppler lidar, sun photometer, and radiosondes to assist in evaluating the meteorological context for the below-cloud and summit observations.
AB - Aqueous chemical processing within cloud and fog water is thought to be a key process in the production and transformation of secondary organic aerosol mass, found abundantly and ubiquitously throughout the troposphere. Yet, significant uncertainty remains regarding the organic chemical reactions taking place within clouds and the conditions under which those reactions occur, owing to the wide variety of organic compounds and their evolution under highly variable conditions when cycled through clouds. Continuous observations from a fixed remote site like Whiteface Mountain (WFM) in New York State and other mountaintop sites have been used to unravel complex multiphase interactions in the past, particularly the conversion of gas-phase emissions of SO2 to sulfuric acid within cloud droplets in the presence of sunlight. These scientific insights led to successful control strategies that reduced aerosol sulfate and cloud water acidity substantially over the following decades. This paper provides an overview of observations obtained during a pilot study that took place at WFM in August 2017 aimed at obtaining a better understanding of Chemical Processing of Organic Compounds within Clouds (CPOC). During the CPOC pilot study, aerosol cloud activation efficiency, particle size distribution, and chemical composition measurements were obtained below-cloud for comparison to routine observations at WFM, including cloud water composition and reactive trace gases. Additional instruments deployed for the CPOC pilot study included a Doppler lidar, sun photometer, and radiosondes to assist in evaluating the meteorological context for the below-cloud and summit observations.
UR - http://www.scopus.com/inward/record.url?scp=85096857137&partnerID=8YFLogxK
U2 - 10.1175/BAMS-D-19-0022.1
DO - 10.1175/BAMS-D-19-0022.1
M3 - 期刊論文
AN - SCOPUS:85096857137
SN - 0003-0007
VL - 101
SP - E1820-E1841
JO - Bulletin of the American Meteorological Society
JF - Bulletin of the American Meteorological Society
IS - 10
ER -