Overall rate constants for diffusion and incorporation in clusters of spheres

Shih Yuan Lu, Yi Ming Yen, Chin Yao Tseng, Heng Kwong Tsao

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

Three numerical schemes and one approximate model for the calculation of overall rate constants for the finite system in a general diffusion and incorporation setting were developed. Yet another approach to obtain the nondiffusion-limited overall rate constant was based on the corresponding data for the diffusion-limited problem. Since the overall rate constant can be more readily obtained for the diffusion-limited cases, it will prove worthwhile to develop an approximate link between the data for the diffusion-limited problem to those for the nondiffusion-limited problem.

Original languageEnglish
Pages (from-to)3431-3439
Number of pages9
JournalJournal of Chemical Physics
Volume117
Issue number7
DOIs
StatePublished - 15 Aug 2002

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