One- and two-dimensional materials containing vanadian oxide: Structures and magnetic properties of Cu(dien)V2O6·H2O and Ni(dien)V2O6 (dien = diethylenetriamine)

Li Min Zheng; Jie Shou Zhao; Kwang Hwa Lii; Li Yi Zhang; Yang Liu; Xin Quan Xin

doi:10.1039/a808839j

One- and two-dimensional materials containing vanadian oxide: Structures and magnetic properties of Cu(dien)V₂O₆·H₂O and Ni(dien)V₂O₆ (dien = diethylenetriamine)

Li Min Zheng, Jie Shou Zhao, Kwang Hwa Lii, Li Yi Zhang, Yang Liu, Xin Quan Xin

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

The structures of a one-dimensional compound Cu(dien)V₂O₆·H₂O 1 and a two-dimensional compound Ni(dien)V₂O₆ 2, where dien is diethylenetriamine, have been determined by X-ray diffraction. The former is composed of corner-sharing VO₄ tetrahedra chains, with Cu(dien)²⁺ fragments attached to every other VO₄ unit. The latter has a layer structure with the V₄O₁₂ tetramers connected by edge-shared NI₂(μ-O)₂(dien)₂⁴⁺ dimers. The layers are further stacked to form one-dimensional channels along the [001] direction. Magnetic susceptibility measurements for both compounds have been performed down to 2 K. Paramagnetic behavior is observed in 1, whereas ferromagnetic interaction is found to be dominant in 2.

Original language	English
Pages (from-to)	939-943
Number of pages	5
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	6
DOIs	https://doi.org/10.1039/a808839j
State	Published - 21 Mar 1999

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10.1039/a808839j

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title = "One- and two-dimensional materials containing vanadian oxide: Structures and magnetic properties of Cu(dien)V2O6·H2O and Ni(dien)V2O6 (dien = diethylenetriamine)",

abstract = "The structures of a one-dimensional compound Cu(dien)V2O6·H2O 1 and a two-dimensional compound Ni(dien)V2O6 2, where dien is diethylenetriamine, have been determined by X-ray diffraction. The former is composed of corner-sharing VO4 tetrahedra chains, with Cu(dien)2+ fragments attached to every other VO4 unit. The latter has a layer structure with the V4O12 tetramers connected by edge-shared NI2(μ-O)2(dien)24+ dimers. The layers are further stacked to form one-dimensional channels along the [001] direction. Magnetic susceptibility measurements for both compounds have been performed down to 2 K. Paramagnetic behavior is observed in 1, whereas ferromagnetic interaction is found to be dominant in 2.",

author = "Zheng, {Li Min} and Zhao, {Jie Shou} and Lii, {Kwang Hwa} and Zhang, {Li Yi} and Yang Liu and Xin, {Xin Quan}",

year = "1999",

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doi = "10.1039/a808839j",

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pages = "939--943",

journal = "Journal of the Chemical Society - Dalton Transactions",

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One- and two-dimensional materials containing vanadian oxide : Structures and magnetic properties of Cu(dien)V₂O₆·H₂O and Ni(dien)V₂O₆ (dien = diethylenetriamine). / Zheng, Li Min; Zhao, Jie Shou; Lii, Kwang Hwa; Zhang, Li Yi; Liu, Yang; Xin, Xin Quan.

In: Journal of the Chemical Society - Dalton Transactions, No. 6, 21.03.1999, p. 939-943.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - One- and two-dimensional materials containing vanadian oxide

T2 - Structures and magnetic properties of Cu(dien)V2O6·H2O and Ni(dien)V2O6 (dien = diethylenetriamine)

AU - Zheng, Li Min

AU - Zhao, Jie Shou

AU - Lii, Kwang Hwa

AU - Zhang, Li Yi

AU - Liu, Yang

AU - Xin, Xin Quan

PY - 1999/3/21

Y1 - 1999/3/21

N2 - The structures of a one-dimensional compound Cu(dien)V2O6·H2O 1 and a two-dimensional compound Ni(dien)V2O6 2, where dien is diethylenetriamine, have been determined by X-ray diffraction. The former is composed of corner-sharing VO4 tetrahedra chains, with Cu(dien)2+ fragments attached to every other VO4 unit. The latter has a layer structure with the V4O12 tetramers connected by edge-shared NI2(μ-O)2(dien)24+ dimers. The layers are further stacked to form one-dimensional channels along the [001] direction. Magnetic susceptibility measurements for both compounds have been performed down to 2 K. Paramagnetic behavior is observed in 1, whereas ferromagnetic interaction is found to be dominant in 2.

AB - The structures of a one-dimensional compound Cu(dien)V2O6·H2O 1 and a two-dimensional compound Ni(dien)V2O6 2, where dien is diethylenetriamine, have been determined by X-ray diffraction. The former is composed of corner-sharing VO4 tetrahedra chains, with Cu(dien)2+ fragments attached to every other VO4 unit. The latter has a layer structure with the V4O12 tetramers connected by edge-shared NI2(μ-O)2(dien)24+ dimers. The layers are further stacked to form one-dimensional channels along the [001] direction. Magnetic susceptibility measurements for both compounds have been performed down to 2 K. Paramagnetic behavior is observed in 1, whereas ferromagnetic interaction is found to be dominant in 2.

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U2 - 10.1039/a808839j

DO - 10.1039/a808839j

M3 - 期刊論文

AN - SCOPUS:33749822202

SP - 939

EP - 943

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

SN - 0300-9246

IS - 6

ER -

One- and two-dimensional materials containing vanadian oxide: Structures and magnetic properties of Cu(dien)V2O6·H2O and Ni(dien)V2O6 (dien = diethylenetriamine)

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One- and two-dimensional materials containing vanadian oxide: Structures and magnetic properties of Cu(dien)V₂O₆·H₂O and Ni(dien)V₂O₆ (dien = diethylenetriamine)