[N(CH2CH2NH3)3][U 3O2F13]·2H2O: A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure

Chih Min Wang; Chia Hsien Liao; Hsiu Mei Lin; Kwang Hwa Lii

doi:10.1021/ic0488280

[N(CH₂CH₂NH₃)₃][U ₃O₂F₁₃]·2H₂O: A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure

Chih Min Wang, Chia Hsien Liao, Hsiu Mei Lin, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The synthesis and characterization of a novel mixed-valent uranium oxyfluoride is described; the inorganic network consists of 2-D [U ₂F₁₀]^2- sheets constructed from corner- and edge-sharing U^IVF₉ tricapped trigonal prisms and 1-D [UO₂F₃]^- chains constructed from edge-sharing U^VIO₂F₅ pentagonal bipyramids with the organic cations and water molecules between the sheets. This is the first example with a hybrid network structure in the system of uranium fluoride or oxyfluoride. The variable-temperature magnetic susceptibility confirms the oxidation state of the uranium ions. Crystal data follow: C₆H₂₅N ₄F₁₃U₃, monoclinic, space group P2₁ (No. 4); a = 8.6876(4) Å, b = 7.3158(4) Å, c = 16.3376(8) Å, β= 93.7285(9)°, V = 1036.2(2) Å³, and Z = 2.

Original language	English
Pages (from-to)	8239-8241
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	26
DOIs	https://doi.org/10.1021/ic0488280
State	Published - 27 Dec 2004

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10.1021/ic0488280

CCDC 260596: Experimental Crystal Structure Determination
Wang, C. (Creator), Liao, C. (Creator), Lin, H. (Creator) & Lii, K. (Contributor), The Cambridge Structural Database, 2005
DOI: 10.5517/cc8r5bh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8r5bh&sid=DataCite
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@article{fc24c66bf4034b4dbaf64b3242262c28,

title = "[N(CH2CH2NH3)3][U 3O2F13]·2H2O: A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure",

abstract = "The synthesis and characterization of a novel mixed-valent uranium oxyfluoride is described; the inorganic network consists of 2-D [U 2F10]2- sheets constructed from corner- and edge-sharing UIVF9 tricapped trigonal prisms and 1-D [UO2F3]- chains constructed from edge-sharing UVIO2F5 pentagonal bipyramids with the organic cations and water molecules between the sheets. This is the first example with a hybrid network structure in the system of uranium fluoride or oxyfluoride. The variable-temperature magnetic susceptibility confirms the oxidation state of the uranium ions. Crystal data follow: C6H25N 4F13U3, monoclinic, space group P21 (No. 4); a = 8.6876(4) {\AA}, b = 7.3158(4) {\AA}, c = 16.3376(8) {\AA}, β= 93.7285(9)°, V = 1036.2(2) {\AA}3, and Z = 2.",

author = "Wang, {Chih Min} and Liao, {Chia Hsien} and Lin, {Hsiu Mei} and Lii, {Kwang Hwa}",

year = "2004",

month = dec,

day = "27",

doi = "10.1021/ic0488280",

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volume = "43",

pages = "8239--8241",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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TY - JOUR

T1 - [N(CH2CH2NH3)3][U 3O2F13]·2H2O

T2 - A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure

AU - Wang, Chih Min

AU - Liao, Chia Hsien

AU - Lin, Hsiu Mei

AU - Lii, Kwang Hwa

PY - 2004/12/27

Y1 - 2004/12/27

N2 - The synthesis and characterization of a novel mixed-valent uranium oxyfluoride is described; the inorganic network consists of 2-D [U 2F10]2- sheets constructed from corner- and edge-sharing UIVF9 tricapped trigonal prisms and 1-D [UO2F3]- chains constructed from edge-sharing UVIO2F5 pentagonal bipyramids with the organic cations and water molecules between the sheets. This is the first example with a hybrid network structure in the system of uranium fluoride or oxyfluoride. The variable-temperature magnetic susceptibility confirms the oxidation state of the uranium ions. Crystal data follow: C6H25N 4F13U3, monoclinic, space group P21 (No. 4); a = 8.6876(4) Å, b = 7.3158(4) Å, c = 16.3376(8) Å, β= 93.7285(9)°, V = 1036.2(2) Å3, and Z = 2.

AB - The synthesis and characterization of a novel mixed-valent uranium oxyfluoride is described; the inorganic network consists of 2-D [U 2F10]2- sheets constructed from corner- and edge-sharing UIVF9 tricapped trigonal prisms and 1-D [UO2F3]- chains constructed from edge-sharing UVIO2F5 pentagonal bipyramids with the organic cations and water molecules between the sheets. This is the first example with a hybrid network structure in the system of uranium fluoride or oxyfluoride. The variable-temperature magnetic susceptibility confirms the oxidation state of the uranium ions. Crystal data follow: C6H25N 4F13U3, monoclinic, space group P21 (No. 4); a = 8.6876(4) Å, b = 7.3158(4) Å, c = 16.3376(8) Å, β= 93.7285(9)°, V = 1036.2(2) Å3, and Z = 2.

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U2 - 10.1021/ic0488280

DO - 10.1021/ic0488280

M3 - 期刊論文

C2 - 15606168

AN - SCOPUS:11144314666

SN - 0020-1669

VL - 43

SP - 8239

EP - 8241

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 26

ER -

[N(CH2CH2NH3)3][U 3O2F13]·2H2O: A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure

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CCDC 260596: Experimental Crystal Structure Determination

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[N(CH₂CH₂NH₃)₃][U ₃O₂F₁₃]·2H₂O: A novel organically templated mixed-valent uranium oxyfluoride with a hybrid network structure