Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Tzu Chau Lin; Shih Huang Chang; Hsiang Yu Hsieh; Zi Ming Chen; Chun Yao Chu

doi:10.1039/d0ra08945a

Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Tzu Chau Lin
, Shih Huang Chang
, Hsiang Yu Hsieh
, Zi Ming Chen
, Chun Yao Chu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10⁻⁸⁰cm⁶s²(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

Original language	English
Pages (from-to)	525-536
Number of pages	12
Journal	RSC Advances
Volume	11
Issue number	1
DOIs	https://doi.org/10.1039/d0ra08945a
State	Published - 24 Nov 2020

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10.1039/d0ra08945a

Development of Novel Three- and Four-Photon-Absorption-Based Optical Power-Limiting Materials: Molecular Design, Synthesis and Characterization
Lin, T.-C. (PI)
1/08/20 → 31/01/22
Project: Research
產學研發中心計畫—中央大學-DSM聯合研發中心:綠色先進功能性材料開發與製程研究(1/3)
Lii, K.-H. (PI)
1/07/20 → 30/06/21
Project: Research
Development and Property Characterization of Novel Wide Band-Gap Small Molecules as the Active Components in the Optical Power-Limiters and Thin-Film Organic Solar Cells( II )
Lin, T.-C. (PI)
1/08/19 → 31/01/21
Project: Research

Cite this

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title = "Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units",

abstract = "Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.",

author = "Lin, \{Tzu Chau\} and Chang, \{Shih Huang\} and Hsieh, \{Hsiang Yu\} and Chen, \{Zi Ming\} and Chu, \{Chun Yao\}",

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T1 - Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

AU - Lin, Tzu Chau

AU - Chang, Shih Huang

AU - Hsieh, Hsiang Yu

AU - Chen, Zi Ming

AU - Chu, Chun Yao

PY - 2020/11/24

Y1 - 2020/11/24

N2 - Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

AB - Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

UR - https://www.scopus.com/pages/publications/85100404733

U2 - 10.1039/d0ra08945a

DO - 10.1039/d0ra08945a

M3 - 期刊論文

AN - SCOPUS:85100404733

SN - 2046-2069

VL - 11

SP - 525

EP - 536

JO - RSC Advances

JF - RSC Advances

IS - 1

ER -

Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Abstract

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Projects

Development of Novel Three- and Four-Photon-Absorption-Based Optical Power-Limiting Materials: Molecular Design, Synthesis and Characterization

產學研發中心計畫—中央大學-DSM聯合研發中心:綠色先進功能性材料開發與製程研究(1/3)

Development and Property Characterization of Novel Wide Band-Gap Small Molecules as the Active Components in the Optical Power-Limiters and Thin-Film Organic Solar Cells( II )

Cite this