Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Tzu Chau Lin; Shih Huang Chang; Hsiang Yu Hsieh; Zi Ming Chen; Chun Yao Chu

doi:10.1039/d0ra08945a

Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Tzu Chau Lin, Shih Huang Chang, Hsiang Yu Hsieh, Zi Ming Chen, Chun Yao Chu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10⁻⁸⁰cm⁶s²(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

Original language	English
Pages (from-to)	525-536
Number of pages	12
Journal	RSC Advances
Volume	11
Issue number	1
DOIs	https://doi.org/10.1039/d0ra08945a
State	Published - 24 Nov 2020

Access to Document

10.1039/d0ra08945a

Development of Novel Three- and Four-Photon-Absorption-Based Optical Power-Limiting Materials: Molecular Design, Synthesis and Characterization
Lin, T.-C. (PI)
1/08/20 → 31/01/22
Project: Research
產學研發中心計畫—中央大學-DSM聯合研發中心:綠色先進功能性材料開發與製程研究(1/3)
Lii, K.-H. (PI)
1/07/20 → 30/06/21
Project: Research
Development and Property Characterization of Novel Wide Band-Gap Small Molecules as the Active Components in the Optical Power-Limiters and Thin-Film Organic Solar Cells( II )
Lin, T.-C. (PI)
1/08/19 → 31/01/21
Project: Research

Cite this

@article{7aa45d194ac6479b9ee06667e7146f2e,

title = "Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units",

abstract = "Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.",

author = "Lin, {Tzu Chau} and Chang, {Shih Huang} and Hsieh, {Hsiang Yu} and Chen, {Zi Ming} and Chu, {Chun Yao}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

month = nov,

day = "24",

doi = "10.1039/d0ra08945a",

language = "???core.languages.en_GB???",

volume = "11",

pages = "525--536",

journal = "RSC Advances",

issn = "2046-2069",

number = "1",

}

TY - JOUR

T1 - Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

AU - Lin, Tzu Chau

AU - Chang, Shih Huang

AU - Hsieh, Hsiang Yu

AU - Chen, Zi Ming

AU - Chu, Chun Yao

PY - 2020/11/24

Y1 - 2020/11/24

N2 - Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

AB - Two chromophoric congeners derived from indenoquinoxaline and oxadiazole are designed, synthesized and characterized for their multi-photon properties in the femtosecond time domain. These two model structures are experimentally found to exhibit strong and widely distributed two- and three-photon activities within the spectral range of 680-1500 nm and the larger congener manifests maximum two- and three-photon absorption cross-section values of 2120 GM (at 750 nm) and ∼85 × 10−80cm6s2(at 1280 nm), respectively. Both two- and three-photon absorption-based optical power-limiting performance of a representative model compound are also evaluated and demonstrated.

UR - http://www.scopus.com/inward/record.url?scp=85100404733&partnerID=8YFLogxK

U2 - 10.1039/d0ra08945a

DO - 10.1039/d0ra08945a

M3 - 期刊論文

AN - SCOPUS:85100404733

SN - 2046-2069

VL - 11

SP - 525

EP - 536

JO - RSC Advances

JF - RSC Advances

IS - 1

ER -

Multi-photon properties of branched chromophores derived from indenoquinoxaline and oxadiazole heterocyclic units

Abstract

Access to Document

Fingerprint

Projects

Development of Novel Three- and Four-Photon-Absorption-Based Optical Power-Limiting Materials: Molecular Design, Synthesis and Characterization

產學研發中心計畫—中央大學-DSM聯合研發中心:綠色先進功能性材料開發與製程研究(1/3)

Development and Property Characterization of Novel Wide Band-Gap Small Molecules as the Active Components in the Optical Power-Limiters and Thin-Film Organic Solar Cells( II )

Cite this