Magnetic order and spin fluctuations in Ni-rich Li0.9Ni1.1O2

C. C. Yang; M. K. Chung; S. Y. Wu; W. H. Li; Y. D. Yao; J. W. Lynn; T. S. Chan; R. S. Liu

doi:10.1016/j.physb.2006.05.236

Magnetic order and spin fluctuations in Ni-rich Li_0.9Ni_1.1O₂

C. C. Yang, M. K. Chung, S. Y. Wu, W. H. Li, Y. D. Yao, J. W. Lynn, T. S. Chan, R. S. Liu

Department of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal and magnetic structures of polycrystalline Li_0.9Ni_1.1O₂ were studied by AC magnetic susceptibility and neutron powder diffraction. The Ni-rich compound crystallizes with rhombohedral symmetry belonging to the space group R over(3, -) m. The AC magnetic susceptibility reveals antiferromagnetic interactions between the Ni moments. Two distinct magnetic components were seen in the magnetic diffraction pattern. One is associated with the ordering of the Ni ions, whereas the other originates from the intra-layer short-range correlations of the Ni ions located on the Li sites. Ni moments order below 180 K, with a saturated moment of 〈μ_Z〉=1.70(8)μ_B..

Original language	English
Pages (from-to)	432-434
Number of pages	3
Journal	Physica B: Condensed Matter
Volume	385-386 I
DOIs	https://doi.org/10.1016/j.physb.2006.05.236
State	Published - 27 Nov 2006

Keywords

LiNiO
Lithium battery
Magnetic structure
Neutron scattering

Access to Document

10.1016/j.physb.2006.05.236

Cite this

@article{b4b55253c84540aa9da40f0f0211565f,

title = "Magnetic order and spin fluctuations in Ni-rich Li0.9Ni1.1O2",

abstract = "The crystal and magnetic structures of polycrystalline Li0.9Ni1.1O2 were studied by AC magnetic susceptibility and neutron powder diffraction. The Ni-rich compound crystallizes with rhombohedral symmetry belonging to the space group R over(3, -) m. The AC magnetic susceptibility reveals antiferromagnetic interactions between the Ni moments. Two distinct magnetic components were seen in the magnetic diffraction pattern. One is associated with the ordering of the Ni ions, whereas the other originates from the intra-layer short-range correlations of the Ni ions located on the Li sites. Ni moments order below 180 K, with a saturated moment of 〈μZ〉=1.70(8)μB..",

keywords = "LiNiO, Lithium battery, Magnetic structure, Neutron scattering",

author = "Yang, {C. C.} and Chung, {M. K.} and Wu, {S. Y.} and Li, {W. H.} and Yao, {Y. D.} and Lynn, {J. W.} and Chan, {T. S.} and Liu, {R. S.}",

note = "Funding Information: The work at NCU was supported by the National Science Council of the Republic of China under Grant number NSC 94-2120-M-008-003. ",

year = "2006",

month = nov,

day = "27",

doi = "10.1016/j.physb.2006.05.236",

language = "???core.languages.en_GB???",

volume = "385-386 I",

pages = "432--434",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

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TY - JOUR

T1 - Magnetic order and spin fluctuations in Ni-rich Li0.9Ni1.1O2

AU - Yang, C. C.

AU - Chung, M. K.

AU - Wu, S. Y.

AU - Li, W. H.

AU - Yao, Y. D.

AU - Lynn, J. W.

AU - Chan, T. S.

AU - Liu, R. S.

N1 - Funding Information: The work at NCU was supported by the National Science Council of the Republic of China under Grant number NSC 94-2120-M-008-003.

PY - 2006/11/27

Y1 - 2006/11/27

N2 - The crystal and magnetic structures of polycrystalline Li0.9Ni1.1O2 were studied by AC magnetic susceptibility and neutron powder diffraction. The Ni-rich compound crystallizes with rhombohedral symmetry belonging to the space group R over(3, -) m. The AC magnetic susceptibility reveals antiferromagnetic interactions between the Ni moments. Two distinct magnetic components were seen in the magnetic diffraction pattern. One is associated with the ordering of the Ni ions, whereas the other originates from the intra-layer short-range correlations of the Ni ions located on the Li sites. Ni moments order below 180 K, with a saturated moment of 〈μZ〉=1.70(8)μB..

AB - The crystal and magnetic structures of polycrystalline Li0.9Ni1.1O2 were studied by AC magnetic susceptibility and neutron powder diffraction. The Ni-rich compound crystallizes with rhombohedral symmetry belonging to the space group R over(3, -) m. The AC magnetic susceptibility reveals antiferromagnetic interactions between the Ni moments. Two distinct magnetic components were seen in the magnetic diffraction pattern. One is associated with the ordering of the Ni ions, whereas the other originates from the intra-layer short-range correlations of the Ni ions located on the Li sites. Ni moments order below 180 K, with a saturated moment of 〈μZ〉=1.70(8)μB..

KW - LiNiO

KW - Lithium battery

KW - Magnetic structure

KW - Neutron scattering

UR - http://www.scopus.com/inward/record.url?scp=33751313876&partnerID=8YFLogxK

U2 - 10.1016/j.physb.2006.05.236

DO - 10.1016/j.physb.2006.05.236

M3 - 期刊論文

AN - SCOPUS:33751313876

SN - 0921-4526

VL - 385-386 I

SP - 432

EP - 434

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter