Ligand Substitution in Cubic Clusters: Surprising Isolation of the Cocrystallization Products of Cu₈(μ₈-Se)[S-P(OEt) ₂]₆ and Cu₆[S₂P(OEt) ₂]₆

Keyphrases

• Co-crystallization 100%
• Copper Cluster 100%
• Cubic Cluster 100%
• Ligand Substitution 100%
• Metal Core 66%
• Octanuclear 66%
• Bridging Ligands 66%
• Toluene 33%
• X-ray Diffraction (XRD) Analysis 33%
• Octahedron 33%
• Repulsion 33%
• Two-component 33%
• Trigonal 33%
• Density Functional Theory 33%
• Intensity Ratio 33%
• Electronegative 33%
• Positive Charge 33%
• Cu(II) 33%
• Percentage Yield 33%
• Copper Atom 33%
• B3LYP Level 33%
• Crystallographic Axes 33%
• 77Se NMR 33%
• 31P NMR Spectra 33%
• 31P Solid-state NMR 33%
• Point Group Symmetry 33%
• Molecular Orbital Calculations 33%
• Sigma-1 Receptor 33%
• Hexanuclear Copper Cluster 33%
• S-containing Ligands 33%
• MO Calculations 33%
• Selenide 33%

Chemistry

• Co Crystallization 100%
• Single Crystal X-Ray Diffraction 50%
• X-Ray Diffraction 50%
• Octahedral Crystal 50%
• Density Functional Theory 50%
• Ab Initio Calculation 50%
• DFT-B3LYP Calculation 50%
• Molecular Orbital 50%
• Trigonal Space Group 50%
• Copper Atom 50%
• Point Group S6 50%
• Selenide 50%
• 77Se NMR Spectroscopy 50%
• 31P NMR Spectrum 50%