Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

Stephen C. Foster; Yen Chu Hsu; Cristino P. Damo; Xianming Liu; Chung Yi Kung; Terry A. Miller

doi:10.1021/j100284a011

Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

Stephen C. Foster, Yen Chu Hsu, Cristino P. Damo, Xianming Liu, Chung Yi Kung, Terry A. Miller

Department of Physics

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.

Original language	English
Pages (from-to)	6766-6769
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	90
Issue number	26
DOIs	https://doi.org/10.1021/j100284a011
State	Published - 1986

Access to Document

10.1021/j100284a011

Cite this

@article{3e5ee936e7e34bedae938432c7c29d8f,

title = "Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure",

abstract = "Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.",

author = "Foster, {Stephen C.} and Hsu, {Yen Chu} and Damo, {Cristino P.} and Xianming Liu and Kung, {Chung Yi} and Miller, {Terry A.}",

year = "1986",

doi = "10.1021/j100284a011",

language = "???core.languages.en_GB???",

volume = "90",

pages = "6766--6769",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

number = "26",

}

TY - JOUR

T1 - Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

AU - Foster, Stephen C.

AU - Hsu, Yen Chu

AU - Damo, Cristino P.

AU - Liu, Xianming

AU - Kung, Chung Yi

AU - Miller, Terry A.

PY - 1986

Y1 - 1986

N2 - Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.

AB - Laser excitation spectra of several alkoxy radicals including methoxy, ethoxy, vinoxy, and isopropoxy have been recorded at low temperature in a supersonic free jet expansion. These spectra in all cases show well-resolved rotational structure. These structures are used to determine the symmetry of the two electronic states involved in the transitions. The symmetries so determined are rationalized in terms of simple molecular orbital theory.

UR - http://www.scopus.com/inward/record.url?scp=0000397779&partnerID=8YFLogxK

U2 - 10.1021/j100284a011

DO - 10.1021/j100284a011

M3 - 期刊論文

AN - SCOPUS:0000397779

SN - 0022-3654

VL - 90

SP - 6766

EP - 6769

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 26

ER -

Implications of the rotationally resolved spectra of the alkoxy radicals for their electronic structure

Abstract

Access to Document

Fingerprint

Cite this