Hydrotreating of residue oil over aluminum borate-supported CoMo and NiMo catalysts

Yu Wen Chen; Ming Chang Tsai

doi:10.1016/S0920-5861(98)00462-3

Hydrotreating of residue oil over aluminum borate-supported CoMo and NiMo catalysts

Yu Wen Chen, Ming Chang Tsai

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Conference article › peer-review

18 Scopus citations

Abstract

A series of aluminum borates with various Al/B ratios were prepared by the precipitation method. These materials were used as the support of CoMo and NiMo catalysts. Hydrotreating of heavy Kuwait atmospheric residuum were carried out in a bench scale trickle bed reactor at 663 K and 7582 kPa. These catalysts were more active than the alumina-supported catalysts. An optimal boria content which gave the highest HDS and HDM activities was located around 4 wt% for both CoMo and NiMo catalysts. In addition, CoMo catalyst was always more active than NiMo catalyst provided the same boria content for both HDS and HDM reactions.

Original language	English
Pages (from-to)	57-61
Number of pages	5
Journal	Catalysis Today
Volume	50
Issue number	1
DOIs	https://doi.org/10.1016/S0920-5861(98)00462-3
State	Published - 6 Apr 1999
Event	Proceedings of the 1997 ACS Symposium at the 214th ACS National Meeting - Las Vegas, NV, United States Duration: 7 Sep 1997 → 11 Sep 1997

Keywords

Aluminum borate
Hydrodemetalation
Hydrodesulfurization
Hydrotreating
Molybdenum catalyst

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10.1016/S0920-5861(98)00462-3

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title = "Hydrotreating of residue oil over aluminum borate-supported CoMo and NiMo catalysts",

abstract = "A series of aluminum borates with various Al/B ratios were prepared by the precipitation method. These materials were used as the support of CoMo and NiMo catalysts. Hydrotreating of heavy Kuwait atmospheric residuum were carried out in a bench scale trickle bed reactor at 663 K and 7582 kPa. These catalysts were more active than the alumina-supported catalysts. An optimal boria content which gave the highest HDS and HDM activities was located around 4 wt% for both CoMo and NiMo catalysts. In addition, CoMo catalyst was always more active than NiMo catalyst provided the same boria content for both HDS and HDM reactions.",

keywords = "Aluminum borate, Hydrodemetalation, Hydrodesulfurization, Hydrotreating, Molybdenum catalyst",

author = "Chen, {Yu Wen} and Tsai, {Ming Chang}",

note = "Funding Information: This research is supported by the Chinese Petroleum Corporation and National Science Council (NSC-82-0402-EOCE-012) of the Republic of China.; Proceedings of the 1997 ACS Symposium at the 214th ACS National Meeting ; Conference date: 07-09-1997 Through 11-09-1997",

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T1 - Hydrotreating of residue oil over aluminum borate-supported CoMo and NiMo catalysts

AU - Chen, Yu Wen

AU - Tsai, Ming Chang

N1 - Funding Information: This research is supported by the Chinese Petroleum Corporation and National Science Council (NSC-82-0402-EOCE-012) of the Republic of China.

PY - 1999/4/6

Y1 - 1999/4/6

N2 - A series of aluminum borates with various Al/B ratios were prepared by the precipitation method. These materials were used as the support of CoMo and NiMo catalysts. Hydrotreating of heavy Kuwait atmospheric residuum were carried out in a bench scale trickle bed reactor at 663 K and 7582 kPa. These catalysts were more active than the alumina-supported catalysts. An optimal boria content which gave the highest HDS and HDM activities was located around 4 wt% for both CoMo and NiMo catalysts. In addition, CoMo catalyst was always more active than NiMo catalyst provided the same boria content for both HDS and HDM reactions.

AB - A series of aluminum borates with various Al/B ratios were prepared by the precipitation method. These materials were used as the support of CoMo and NiMo catalysts. Hydrotreating of heavy Kuwait atmospheric residuum were carried out in a bench scale trickle bed reactor at 663 K and 7582 kPa. These catalysts were more active than the alumina-supported catalysts. An optimal boria content which gave the highest HDS and HDM activities was located around 4 wt% for both CoMo and NiMo catalysts. In addition, CoMo catalyst was always more active than NiMo catalyst provided the same boria content for both HDS and HDM reactions.

KW - Aluminum borate

KW - Hydrodemetalation

KW - Hydrodesulfurization

KW - Hydrotreating

KW - Molybdenum catalyst

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AN - SCOPUS:0343207286

SN - 0920-5861

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JF - Catalysis Today

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T2 - Proceedings of the 1997 ACS Symposium at the 214th ACS National Meeting

Y2 - 7 September 1997 through 11 September 1997

ER -

Hydrotreating of residue oil over aluminum borate-supported CoMo and NiMo catalysts

Abstract

Keywords

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