Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin

Hew Der Wu; Chen Chi M. Ma; Peter P. Chu

doi:10.1016/S0032-3861(97)00067-0

Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin

Hew Der Wu, Chen Chi M. Ma, Peter P. Chu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The hydrogen bond formation between novolac type phenolic resin (phenolic) and polyhydroxyl ether of bisphenol A (Phenoxy resin) were verified by infra-red (i.r.), gel permeation chromatography (g.p.c.) and nuclear magnetic resonance (n.m.r.). The i.r. spectrum of the 'free' hydroxyl group of the blend shows a maximum absorption area with 25 wt% phenoxy which coincides with the lowest point of the glass transition temperature (T_g) is observed. In the phenolic-rich region, almost all the hydroxyls of the phenoxy interact with the phenolic resin. The carbonyl group of benzoylated phenoxy (Bz-phenoxy) confirms further the association of hydrogen bonding with hydroxyls of phenolic resin. It was found that phenolic resin interpenetrates with the phenoxy and Bz-phenoxy and causes significant decreasing of T_g.

Original language	English
Pages (from-to)	5419-5429
Number of pages	11
Journal	Polymer
Volume	38
Issue number	21
DOIs	https://doi.org/10.1016/S0032-3861(97)00067-0
State	Published - Oct 1997

Keywords

Blend
Phenolic
Phenoxy

Access to Document

10.1016/S0032-3861(97)00067-0

Cite this

@article{46b38ca5a73e4076bcf61fb12f26eaaf,

title = "Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin",

abstract = "The hydrogen bond formation between novolac type phenolic resin (phenolic) and polyhydroxyl ether of bisphenol A (Phenoxy resin) were verified by infra-red (i.r.), gel permeation chromatography (g.p.c.) and nuclear magnetic resonance (n.m.r.). The i.r. spectrum of the 'free' hydroxyl group of the blend shows a maximum absorption area with 25 wt% phenoxy which coincides with the lowest point of the glass transition temperature (Tg) is observed. In the phenolic-rich region, almost all the hydroxyls of the phenoxy interact with the phenolic resin. The carbonyl group of benzoylated phenoxy (Bz-phenoxy) confirms further the association of hydrogen bonding with hydroxyls of phenolic resin. It was found that phenolic resin interpenetrates with the phenoxy and Bz-phenoxy and causes significant decreasing of Tg.",

keywords = "Blend, Phenolic, Phenoxy",

author = "Wu, {Hew Der} and Ma, {Chen Chi M.} and Chu, {Peter P.}",

note = "Funding Information: ACKNOWLEDGEMENT This research was financially supported by National Science Council, Taiwan, Republic of China, under Contract No. NSC-85-2216-E007-007.",

year = "1997",

month = oct,

doi = "10.1016/S0032-3861(97)00067-0",

language = "???core.languages.en_GB???",

volume = "38",

pages = "5419--5429",

journal = "Polymer",

issn = "0032-3861",

number = "21",

}

TY - JOUR

T1 - Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin

AU - Wu, Hew Der

AU - Ma, Chen Chi M.

AU - Chu, Peter P.

N1 - Funding Information: ACKNOWLEDGEMENT This research was financially supported by National Science Council, Taiwan, Republic of China, under Contract No. NSC-85-2216-E007-007.

PY - 1997/10

Y1 - 1997/10

N2 - The hydrogen bond formation between novolac type phenolic resin (phenolic) and polyhydroxyl ether of bisphenol A (Phenoxy resin) were verified by infra-red (i.r.), gel permeation chromatography (g.p.c.) and nuclear magnetic resonance (n.m.r.). The i.r. spectrum of the 'free' hydroxyl group of the blend shows a maximum absorption area with 25 wt% phenoxy which coincides with the lowest point of the glass transition temperature (Tg) is observed. In the phenolic-rich region, almost all the hydroxyls of the phenoxy interact with the phenolic resin. The carbonyl group of benzoylated phenoxy (Bz-phenoxy) confirms further the association of hydrogen bonding with hydroxyls of phenolic resin. It was found that phenolic resin interpenetrates with the phenoxy and Bz-phenoxy and causes significant decreasing of Tg.

AB - The hydrogen bond formation between novolac type phenolic resin (phenolic) and polyhydroxyl ether of bisphenol A (Phenoxy resin) were verified by infra-red (i.r.), gel permeation chromatography (g.p.c.) and nuclear magnetic resonance (n.m.r.). The i.r. spectrum of the 'free' hydroxyl group of the blend shows a maximum absorption area with 25 wt% phenoxy which coincides with the lowest point of the glass transition temperature (Tg) is observed. In the phenolic-rich region, almost all the hydroxyls of the phenoxy interact with the phenolic resin. The carbonyl group of benzoylated phenoxy (Bz-phenoxy) confirms further the association of hydrogen bonding with hydroxyls of phenolic resin. It was found that phenolic resin interpenetrates with the phenoxy and Bz-phenoxy and causes significant decreasing of Tg.

KW - Blend

KW - Phenolic

KW - Phenoxy

UR - http://www.scopus.com/inward/record.url?scp=0031245299&partnerID=8YFLogxK

U2 - 10.1016/S0032-3861(97)00067-0

DO - 10.1016/S0032-3861(97)00067-0

M3 - 期刊論文

AN - SCOPUS:0031245299

VL - 38

SP - 5419

EP - 5429

JO - Polymer

JF - Polymer

SN - 0032-3861

IS - 21

ER -

Hydrogen bonding in the novolac type phenolic resin blended with phenoxy resin

Abstract

Keywords

Access to Document

Fingerprint

Cite this