High-resolution Fourier-transform infrared spectrum of the13CH3F fundamental band of13CH3F

D. Papoušek; Yen Chu Hsu; S. Klee; M. Winnewisser

doi:10.1007/BF03156415

High-resolution Fourier-transform infrared spectrum of the¹³CH₃F fundamental band of¹³CH₃F

D. Papoušek, Yen Chu Hsu, S. Klee, M. Winnewisser

Department of Physics

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The v₆ vibration-rotational band of¹³CH₃F has been measured in the range 1070-1260 cm^-1 using a Fourier-transform spectrometer with unapodized resolution 0.0027 cm^-1. The wavenumbers of 1262 vibration-rotational transitions to the v₆=1 (E) vibrational state have been assigned and fitted by least squares with the standard deviation of the fit 1.31×10^-4 cm^-1. This made it possible to determine 19 spectroscopical parameters of the v₆=1 state including parameters of the Δk=±2, Δl=∓2 and Δk=±4, Δl=∓2 interactions leading to the A₁-A₂ splittings of many rotational levels with kl=+1 and kl=-2.

Original language	English
Pages (from-to)	419-426
Number of pages	8
Journal	Acta Physica Hungarica
Volume	74
Issue number	4
DOIs	https://doi.org/10.1007/BF03156415
State	Published - Sep 1994

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title = "High-resolution Fourier-transform infrared spectrum of the13CH3F fundamental band of13CH3F",

abstract = "The v6 vibration-rotational band of13CH3F has been measured in the range 1070-1260 cm-1 using a Fourier-transform spectrometer with unapodized resolution 0.0027 cm-1. The wavenumbers of 1262 vibration-rotational transitions to the v6=1 (E) vibrational state have been assigned and fitted by least squares with the standard deviation of the fit 1.31×10-4 cm-1. This made it possible to determine 19 spectroscopical parameters of the v6=1 state including parameters of the Δk=±2, Δl=∓2 and Δk=±4, Δl=∓2 interactions leading to the A1-A2 splittings of many rotational levels with kl=+1 and kl=-2.",

author = "D. Papou{\v s}ek and Hsu, {Yen Chu} and S. Klee and M. Winnewisser",

year = "1994",

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T1 - High-resolution Fourier-transform infrared spectrum of the13CH3F fundamental band of13CH3F

AU - Papoušek, D.

AU - Hsu, Yen Chu

AU - Klee, S.

AU - Winnewisser, M.

PY - 1994/9

Y1 - 1994/9

N2 - The v6 vibration-rotational band of13CH3F has been measured in the range 1070-1260 cm-1 using a Fourier-transform spectrometer with unapodized resolution 0.0027 cm-1. The wavenumbers of 1262 vibration-rotational transitions to the v6=1 (E) vibrational state have been assigned and fitted by least squares with the standard deviation of the fit 1.31×10-4 cm-1. This made it possible to determine 19 spectroscopical parameters of the v6=1 state including parameters of the Δk=±2, Δl=∓2 and Δk=±4, Δl=∓2 interactions leading to the A1-A2 splittings of many rotational levels with kl=+1 and kl=-2.

AB - The v6 vibration-rotational band of13CH3F has been measured in the range 1070-1260 cm-1 using a Fourier-transform spectrometer with unapodized resolution 0.0027 cm-1. The wavenumbers of 1262 vibration-rotational transitions to the v6=1 (E) vibrational state have been assigned and fitted by least squares with the standard deviation of the fit 1.31×10-4 cm-1. This made it possible to determine 19 spectroscopical parameters of the v6=1 state including parameters of the Δk=±2, Δl=∓2 and Δk=±4, Δl=∓2 interactions leading to the A1-A2 splittings of many rotational levels with kl=+1 and kl=-2.

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JO - Acta Physica Hungarica

JF - Acta Physica Hungarica

IS - 4

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High-resolution Fourier-transform infrared spectrum of the13CH3F fundamental band of13CH3F

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High-resolution Fourier-transform infrared spectrum of the¹³CH₃F fundamental band of¹³CH₃F