High alcohol synthesis from CO and H2 on ruthenium catalysts

Yu‐Wen ‐W Chen

doi:10.1002/cjce.5450640527

High alcohol synthesis from CO and H₂ on ruthenium catalysts

Yu‐Wen ‐W Chen

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A Ru/MoO₂ catalyst was found to be active for the synthesis gas conversion to straight chain primary alcohols. Potassium carbonate was effective for enhancing high alcohol formation. The carbon number distribution of the alcoholic products followed the Anderson‐Schulz‐Flory distribution which gave chain growth probabilities of 0.27–0.35. In addition, the Ru/MoO₂ catalysts are significantly more sulfur resistant than a Ru/Al₂O₃ catalyst. The higher sulfur resistance of these catalysts is mainly due to their higher sulfur adsorption capacities.

Original language	English
Pages (from-to)	875-878
Number of pages	4
Journal	The Canadian Journal of Chemical Engineering
Volume	64
Issue number	5
DOIs	https://doi.org/10.1002/cjce.5450640527
State	Published - Oct 1986

Access to Document

10.1002/cjce.5450640527

Cite this

@article{c71e0c4db9bb411b9f55097869e2ec89,

title = "High alcohol synthesis from CO and H2 on ruthenium catalysts",

abstract = "A Ru/MoO2 catalyst was found to be active for the synthesis gas conversion to straight chain primary alcohols. Potassium carbonate was effective for enhancing high alcohol formation. The carbon number distribution of the alcoholic products followed the Anderson‐Schulz‐Flory distribution which gave chain growth probabilities of 0.27–0.35. In addition, the Ru/MoO2 catalysts are significantly more sulfur resistant than a Ru/Al2O3 catalyst. The higher sulfur resistance of these catalysts is mainly due to their higher sulfur adsorption capacities.",

author = "Chen, {Yu‐Wen ‐W}",

year = "1986",

month = oct,

doi = "10.1002/cjce.5450640527",

language = "???core.languages.en_GB???",

volume = "64",

pages = "875--878",

journal = "The Canadian Journal of Chemical Engineering",

issn = "0008-4034",

number = "5",

}

TY - JOUR

T1 - High alcohol synthesis from CO and H2 on ruthenium catalysts

AU - Chen, Yu‐Wen ‐W

PY - 1986/10

Y1 - 1986/10

N2 - A Ru/MoO2 catalyst was found to be active for the synthesis gas conversion to straight chain primary alcohols. Potassium carbonate was effective for enhancing high alcohol formation. The carbon number distribution of the alcoholic products followed the Anderson‐Schulz‐Flory distribution which gave chain growth probabilities of 0.27–0.35. In addition, the Ru/MoO2 catalysts are significantly more sulfur resistant than a Ru/Al2O3 catalyst. The higher sulfur resistance of these catalysts is mainly due to their higher sulfur adsorption capacities.

AB - A Ru/MoO2 catalyst was found to be active for the synthesis gas conversion to straight chain primary alcohols. Potassium carbonate was effective for enhancing high alcohol formation. The carbon number distribution of the alcoholic products followed the Anderson‐Schulz‐Flory distribution which gave chain growth probabilities of 0.27–0.35. In addition, the Ru/MoO2 catalysts are significantly more sulfur resistant than a Ru/Al2O3 catalyst. The higher sulfur resistance of these catalysts is mainly due to their higher sulfur adsorption capacities.

UR - http://www.scopus.com/inward/record.url?scp=84989406564&partnerID=8YFLogxK

U2 - 10.1002/cjce.5450640527

DO - 10.1002/cjce.5450640527

M3 - 期刊論文

AN - SCOPUS:84989406564

SN - 0008-4034

VL - 64

SP - 875

EP - 878

JO - The Canadian Journal of Chemical Engineering

JF - The Canadian Journal of Chemical Engineering

IS - 5

ER -

High alcohol synthesis from CO and H2 on ruthenium catalysts

Abstract

Access to Document

Fingerprint

Cite this

High alcohol synthesis from CO and H₂ on ruthenium catalysts