Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Yi Hao Huang, Wei Shang Lo, Yun Wei Kuo, Wen Jin Chen, Chia Her Lin, Fa Kuen Shieh

Research output: Contribution to journalArticlepeer-review

69 Scopus citations

Abstract

A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.

Original languageEnglish
Pages (from-to)5818-5821
Number of pages4
JournalChemical Communications
Volume53
Issue number43
DOIs
StatePublished - 2017

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